Dichloroplatinum;4,9-dichloroquinolino[7,8-h]quinoline | 374074-96-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Dichloroplatinum;4,9-dichloroquinolino[7,8-h]quinoline
• CAS: 374074-96-1
• 化学式: C₁₆H₈Cl₄N₂Pt
• 分子量: 565.145
• InChiKey: ZNFRZCFIBPWNBE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.62
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  、 4,9-Dichlorchino<7,8-h>chinolin 以 二氯甲烷 为溶剂， 以91.2%的产率得到Dichloroplatinum;4,9-dichloroquinolino[7,8-h]quinoline
  参考文献：
  名称：

  Transition Metal Complexes with the Proton Sponge 4,9-Dichloroquino[7,8-h]quinoline: Highly Twisted Aromatic Systems and an Extreme “Out-of-Plane” Position of the Coordinated Transition Metal Atom

  摘要：

  An extremely high thermal and chemical stability as well as a unique "out-of-plane" position of the metal atom is shown by the first stable transition metal complexes formed with the proton sponge 1 as the ligand. The properties of these complexes await wide application in catalysis and medicine.

  DOI：

  10.1002/1521-3773(20010903)40:17<3182::aid-anie3182>3.0.co;2-j

文献信息

• Transition Metal Complexes with the Proton Sponge 4,9-Dichloroquino[7,8-h]quinoline: Highly Twisted Aromatic Systems and an Extreme “Out-of-Plane” Position of the Coordinated Transition Metal Atom
  作者：Hans-Ulrich Wüstefeld、William C. Kaska、Ferdi Schüth、Galen D. Stucky、Xianhui Bu、Bernt Krebs

  DOI：10.1002/1521-3773(20010903)40:17<3182::aid-anie3182>3.0.co;2-j

  日期：2001.9.3

  An extremely high thermal and chemical stability as well as a unique "out-of-plane" position of the metal atom is shown by the first stable transition metal complexes formed with the proton sponge 1 as the ligand. The properties of these complexes await wide application in catalysis and medicine.