2,2'-methanediyl-bis-cyclohexanol | 6556-80-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2'-methanediyl-bis-cyclohexanol
• 英文别名: 2,2'-Methandiyl-bis-cyclohexanol；Cyclohexanol, 2,2'-methylenebis-；2-[(2-hydroxycyclohexyl)methyl]cyclohexan-1-ol
• CAS: 6556-80-5；6556-81-6；6556-82-7；6556-88-3；14794-76-4；14794-77-5；14794-78-6；18938-70-0；18938-71-1；63427-19-0；66610-34-2
• 化学式: C₁₃H₂₄O₂
• 分子量: 212.332
• InChiKey: LKYPEPZUSDXZTC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2'-methanediyl-bis-cyclohexanol 生成 bis-[2-(3,5-dinitro-benzoyloxy)-cyclohexyl]-methane
  参考文献：
  名称：

  Allwinn et al., Bulletin de la Societe Chimique de France, 1958, p. 1178

  摘要：

  DOI：
• 作为产物：
  描述：

  bis(2-oxocyclohexyl)methane 在 lithium aluminium tetrahydride 、 乙醚 作用下， 生成 2,2'-methanediyl-bis-cyclohexanol
  参考文献：
  名称：

  Allwinn et al., Bulletin de la Societe Chimique de France, 1958, p. 1178

  摘要：

  DOI：

文献信息

• Curable epoxy resin composition
  申请人：ASAHI DENKA KOGYO KABUSHIKI KAISHA

  公开号：EP0197458A2

  公开（公告）日：1986-10-15

  A thermosetting epoxy resin composition of one pack type is provided which contains as indispensable constituents (I) an epoxy resin containing more than one adjacent epoxy groups on the average in the molecule and (II) curing amount or curing-accelerating amount of a compound obtained by reacting (a) a specified amine/epoxy adduct with (b) phenolic , resin(s) and/or polyhydric phenol compound(s) in a weight ratio of (a) to (b) of 1/0.1 to 1/0.8. The composition of the present invention has excellent storage stability and it is curable at a relatively low temperature to form a cured product having excellent mechanical strength, adhesiveness and water resistance.

  本发明提供了一种单组分热固性环氧树脂组合物，其不可或缺的成分包括：(I) 分子中平均含有一个以上相邻环氧基团的环氧树脂；(II) 固化量或固化加速量的化合物，该化合物由(a)特定的胺/环氧加合物与(b)酚醛树脂和/或多羟基酚化合物反应而得，(a)与(b)的重量比为 1/0.1 至 1/0.8。本发明的组合物具有极佳的储存稳定性，可在相对较低的温度下固化，形成具有极佳机械强度、粘合性和耐水性的固化产品。
• Process for producing alicyclic diketone compounds
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0697389A1

  公开（公告）日：1996-02-21

  There is provided a process for producing an alicyclic diketone compound represented by the formula (1) wherein X is a single bond, -CH₂-, -C(CH₃)₂-, -O- or -SO₂-, R¹ and R² each represents an alkyl group having 1 to 6 carbon atoms, m and n are 0 to 2, comprising dehydrogenating an alicyclic diol compound represented by the formula (2) wherein X, R¹, R², m and n are as defined above in a liquid phase in the presence of at least one member selected from the group consisting of copper type catalysts and Raney type catalysts.

  提供了一种生产由式（1）表示的脂环族二酮化合物的工艺 其中 X 为单键、-CH₂-、-C(CH₃)₂-、-O- 或-SO₂-，R¹ 和 R² 分别代表具有 1 至 6 个碳原子的烷基，m 和 n 为 0 至 2，包括将式 (2) 所代表的脂环族二元醇化合物脱氢 其中 X、R¹、R²、m 和 n 如上文所定义，在液相中，在至少一种选自铜催化剂和雷尼催化剂组成的组中的催化剂存在下进行。
• Kharchenko, V. G.; Terekhin, A. A.; Shebaldova, A. D., Journal of Organic Chemistry USSR (English Translation), 1981, vol. 17, p. 768 - 769
  作者：Kharchenko, V. G.、Terekhin, A. A.、Shebaldova, A. D.、Kravtsova, V. N.

  DOI：——

  日期：——
• Colonge et al., Bulletin de la Societe Chimique de France, 1957, p. 342,345
  作者：Colonge et al.

  DOI：——

  日期：——
• Hydroacridines XVIII [1]. Synthesis and NMR Spectroscopic Investigation of(4aα,8aβ,9aα,10aβ)-Tetradecahydroacridine and Some of its Derivatives
  作者：Francisc Potmischil、Friedrich W. Vierhapper、Hermann Kalchhauser

  DOI：10.1007/pl00000108

  日期：1998.5

  The reductive amination of (R*,R*)-2,2'-methylene-bis-cyclohexanone (1) with methylamine and potassium borohydride affords a mixture of (4a alpha,8a beta,9a alpha,10a beta)- and (4a alpha,8a alpha,9a beta,10a alpha)-tetradecahydro-10-methylacridine (2, 3) in a ratio of approximately 1.3:1 in 57% overall yield. By N-demethylation of 2, via the N-nitrosamine 4 the first synthesis of (4a alpha,8a beta,9a alpha,10a beta)-tetradecahydroacridine (5) could be performed. The relative configurations and conformations of compounds 2-5 as well as the barrier of conformational inversion of 5(Delta G(300)(#), = 55.5 +/- 0.4kJ.mol(-1)) were determined by NMR spectroscopy.