3-Formyl-4-isopropoxyphenyl pivalate | 321922-23-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 3-Formyl-4-isopropoxyphenyl pivalate
• 英文别名: (3-formyl-4-propan-2-yloxyphenyl) 2,2-dimethylpropanoate
• CAS: 321922-23-0
• 化学式: C₁₅H₂₀O₄
• 分子量: 264.321
• InChiKey: YXACSUVNWNRLGV-UHFFFAOYSA-N

物化性质

• 沸点：
  375.2±32.0 °C(Predicted)
• 密度：
  1.075±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-Formyl-4-isopropoxyphenyl pivalate 在 sodium hydride 、 lithium hexamethyldisilazane 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 20.33h， 生成
  参考文献：
  名称：

  Self-Supported Oligomeric Grubbs/Hoveyda-Type Ru−Carbene Complexes for Ring-Closing Metathesis

  摘要：

  On the basis of the release-return metathesis mechanism, self-supported oligomeric Grubbs/Hoveyda-type Ru-carbene complexes have been designed and synthesized as a new type of recoverable catalyst for ring-closing metathesis. The catalytic activities of the self-supported oligomeric Ru-carbene complex in ring-closing metathesis are comparable to those of their homogeneous counterpart as they work homogeneously and are recovered heterogeneously.

  DOI：

  10.1021/ol7016774
• 作为产物：
  描述：

  2,5-二羟基苯甲醛 在 potassium carbonate 、 caesium carbonate 、 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 生成 3-Formyl-4-isopropoxyphenyl pivalate
  参考文献：
  名称：

  Self-Supported Oligomeric Grubbs/Hoveyda-Type Ru−Carbene Complexes for Ring-Closing Metathesis

  摘要：

  On the basis of the release-return metathesis mechanism, self-supported oligomeric Grubbs/Hoveyda-type Ru-carbene complexes have been designed and synthesized as a new type of recoverable catalyst for ring-closing metathesis. The catalytic activities of the self-supported oligomeric Ru-carbene complex in ring-closing metathesis are comparable to those of their homogeneous counterpart as they work homogeneously and are recovered heterogeneously.

  DOI：

  10.1021/ol7016774

文献信息

• A Soluble Polymer-Bound Ruthenium Carbene Complex: A Robust and Reusable Catalyst for Ring-Closing Olefin Metathesis
  作者：Qingwei Yao

  DOI：10.1002/1521-3773(20001103)39:21<3896::aid-anie3896>3.0.co;2-8

  日期：2000.11.3