降冰片烯醇 | 60638-01-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 降冰片烯醇
• 英文名称: norborn-2-en-1-ol
• 英文别名: norbornenyl alcohol；norbornenol；Bicyclo[2.2.1]hept-2-EN-1-OL
• CAS: 60638-01-9
• 化学式: C₇H₁₀O
• 分子量: 110.156
• InChiKey: BXKVMQAJHSXYHX-UHFFFAOYSA-N

物化性质

• 沸点：
  175.7±9.0 °C(Predicted)
• 密度：
  1.220±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  降冰片烯醇 在 sodium hydroxide 、 硼烷四氢呋喃络合物 、 双氧水 、 pyridinium chlorochromate 作用下， 以 二氯甲烷 为溶剂， 反应 4.5h， 生成 1-methoxynorbornan-2-one
  参考文献：
  名称：

  某些1-取代的Norborn-2-enes的硼氢化和加氢氧合†

  摘要：

  在动力学控制下，1-取代的降冰片-2-烯11-13和18与亲电试剂优先在2位反应。氧化汞化中的区域选择性高于氢硼化和与氯化钯水溶液反应中的区域选择性。

  DOI：

  10.1002/hlca.19830660842
• 作为产物：
  描述：

  norbornenyl acetate 在 lithium aluminium tetrahydride 作用下， 生成 降冰片烯醇
  参考文献：
  名称：

  Mironov,V.A. et al., Journal of Organic Chemistry USSR (English Translation), 1976, vol. 12, p. 1422 - 1427

  摘要：

  DOI：

文献信息

• Single component, phosphine-free, initiators for ethylene homopolymerization and copolymerization with functionalized co-monomers
  申请人：Bazan C. Guillermo

  公开号：US20070225456A1

  公开（公告）日：2007-09-27

  Novel phosphine-free non-ionic single catalysts, and method for making such catalysts, for the homo-polymerization and copolymerization of olefins such as ethylene, a-olefins and functionalized olefins without the use of additional co-activators, are disclosed. These phosphine-free non-ionic single catalysts are also active for co-polymerization of olefins with monomers with polar functionalities. The catalyst of this invention comprise of a late transition metal with a chelating monoanionic ligand, an R group and a neutral 2 electron donor ligand. Catalysts are prepared by the oxidative addition of benzylhalide (halide=Cl, Br or I) to an appropriate metal source in the presence of a stabilizing agent, such as nitrogen based ligands, followed by the addition of the deprotonated form of the chelating ligand.

  无磷非离子单一催化剂的制备方法及其用途，用于乙烯、α-烯烃和功能性烯烃的均聚和共聚，无需使用额外的共激活剂。这些无磷非离子单一催化剂对与具有极性功能的单体进行共聚也具有活性。本发明的催化剂包括一个晚过渡金属、一个螯合单阴离子配体、一个R基团和一个中性两电子供体配体。催化剂的制备方法是将苯甲基卤化物（卤素=Cl、Br或I）在存在稳定剂（如基于氮的配体）的情况下，与适当的金属源进行氧化加成，然后加入螯合配体的去质子化形式。
• Optically active compound and photosensitive resin composition
  申请人：——

  公开号：US20030211421A1

  公开（公告）日：2003-11-13

  A photoactive compound is used in combination with a photosensitizer, represented by the following formula (1): A −[( J ) m −( X-Pro )] n (1) wherein A represents a hydrophobic unit comprising at least one kind of hydrophobic groups selected from a hydrocarbon group and a heterocyclic group, J represents a connecting group, X-Pro represents a hydrophilic group protected by a protective group Pro which is removable by light exposure, m represents 0 or 1, and n represents an integer of not less than 1. The protective group Pro may be removable by light exposure in association with the photosensitizer (especially, a photo acid generator), or may be a hydrophobic protective group. The hydrophilic group may be a hydroxyl group or a carboxyl group. The photoactive compound has high sensitivity to a light source of short wavelength beams, for resist application, therefore, the photoactive compound is advantageously used for forming a pattern with high resolution.

  一种光活性化合物与光敏剂结合使用，由以下公式（1）表示： A −[( J ) m −( X-Pro )] n (1) 其中，A代表至少包括一种从烃基和杂环基中选择的疏水基的疏水单元，J代表连接基团，X-Pro代表由光照可去除的保护基团Pro保护的亲水基团，m代表0或1，n代表不少于1的整数。 保护基团Pro可以与光敏剂（特别是光酸发生剂）一起通过光照可去除，也可以是疏水保护基团。亲水基团可以是羟基或羧基。光活性化合物对短波长光源具有很高的敏感性，用于光刻应用，因此，该光活性化合物有利于形成具有高分辨率的图案。
• Metal catalyst for olefin polymerization and co-polymerization with functional monomers
  申请人：——

  公开号：US20040171479A1

  公开（公告）日：2004-09-02

  A catalyst is disclosed for the polymerization and co-polymerization of olefins with functionalized monomers. The catalyst is formed from a combination of two neutral metal complexes, L( i Pr 2 )M(CH 2 Ph)(PMe 3 )[L=N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamide] and M(COD) 2 (COD=cyclooctadiene). The catalyst displays a unique mode of action and performs at ambient conditions producing high molecular weight polyolefins and co-polymers with functional groups. The polymerized olefins include ethylene, &agr;-olefins and functionalized olefins.

  本发明揭示了一种用于与功能化单体共聚合的烯烃聚合的催化剂。该催化剂由两种中性金属络合物L(iPr2)M(CH2Ph)(PMe3) [其中L=N-(2,6-二异丙基苯基)-2-(2,6-二异丙基苯亚亚胺)丙酰胺]和M(COD)2(COD=cyclooctadiene)的组合形成。该催化剂表现出独特的作用方式，并在常温下产生具有功能基的高分子量聚烯烃和共聚物。聚合的烯烃包括乙烯、α-烯烃和功能化烯烃。
• OPTICALLY ACTIVE COMPOUND AND PHOTOSENSITIVE RESIN COMPOSITION
  申请人：Kansai Research Institute, Inc.

  公开号：EP1375463A1

  公开（公告）日：2004-01-02

  A photoactive compound is used in combination with a photosensitizer, represented by the following formula (1):         A-[(J)m-(X-Pro)]n     (1)    wherein A represents a hydrophobic unit comprising at least one kind of hydrophobic groups selected from a hydrocarbon group and a heterocyclic group, J represents a connecting group, X-Pro represents a hydrophilic group protected by a protective group Pro which is removable by light exposure, m represents 0 or 1, and n represents an integer of not less than 1. The protective group Pro may be removable by light exposure in association with the photosensitizer (especially, a photo acid generator), or may be a hydrophobic protective group. The hydrophilic group may be a hydroxyl group or a carboxyl group. The photoactive compound has high sensitivity to a light source of short wavelength beams, for resist application, therefore, the photoactive compound is advantageously used for forming a pattern with high resolution.

  光活性化合物与光敏剂结合使用，光敏剂由下式（1）表示： A-[(J)m-(X-Pro)]n (1) 其中 A 代表疏水单元，包括至少一种选自烃基和杂环基的疏水基团；J 代表连接基团；X-Pro 代表亲水基团，该亲水基团受保护基团 Pro 的保护，该保护基团可通过光照去除；m 代表 0 或 1；n 代表不小于 1 的整数。 保护基 Pro 可以通过与光敏剂（特别是光酸发生器）一起进行光照射而去除，也可以是疏水保护基。亲水基团可以是羟基或羧基。光活性化合物对短波长光束的光源具有很高的灵敏度，因此在抗蚀剂应用中，光活性化合物可用于形成具有高分辨率的图案。
• A metal catalyst for olefin polymerization and co-polymerization with functional monomers
  申请人：The Regents Of the University of California

  公开号：EP2305721A2

  公开（公告）日：2011-04-06

  A copolymer is disclosed having the general formula of R5CH=CH2. The group R5 can be hydrogen, a hydrocarbyl group, cyclopentene, styrene, norbornene or a polar olefin. The copolymer can be a block copolymer, a star-shaped polymer, a graft polymer or an alternating polymer. There is also disclosed a method of obtaining a polyolefin. The method includes the step of polymerizing or co-polymerizing an olefin in the presence of a catalyst.

  本发明公开了一种具有通式 R5CH=CH2 的共聚物。基团 R5 可以是氢、烃基、环戊烯、苯乙烯、降冰片烯或极性烯烃。共聚物可以是嵌段共聚物、星形聚合物、接枝聚合物或交替聚合物。还公开了一种获得聚烯烃的方法。该方法包括在催化剂存在下聚合或共聚合烯烃的步骤。