copper(II)(N-o-OMe-phenylpyrrole-2-aldiminate)2 | 146082-32-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: copper(II)(N-o-OMe-phenylpyrrole-2-aldiminate)2
• CAS: 146082-32-8
• 化学式: C₂₄H₂₂CuN₄O₂
• 分子量: 462.01
• InChiKey: WOZYELUCJLBXKZ-ZNVPEIAMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  iron perchlorate hexahydrate 、 copper(II)(N-o-OMe-phenylpyrrole-2-aldiminate)2 以 二氯甲烷 、 丙酮 为溶剂， 生成 (N-o-OMe-phenylpyrrole-2-aldiminium) perchlorate
  参考文献：
  名称：

  Synthesis and characterization of copper and nickel complexes with N-arylpyrrole-2-aldimines

  摘要：

  A series of 17N-arylpyrrole-2-aldimine ligands has been synthesized by condensation of pyrrole-2-carboxaldehyde and substituted anilines. All CuL2 complexes are square, whereas NiL2 compounds are square, tetrahedral or eventually present a square half arrow right over half arrow left tetrahedral equilibrium. Attempts of chemical oxidation have shown the existence of nickel(III) and copper(III) in solution.

  DOI：

  10.1016/s0277-5387(00)80241-7
• 作为产物：
  描述：

  2-(1H-pyrrol-2-ylmethylideneamino)anisole 、 copper diacetate 以 乙醇 为溶剂， 生成 copper(II)(N-o-OMe-phenylpyrrole-2-aldiminate)2
  参考文献：
  名称：

  Synthesis and characterization of copper and nickel complexes with N-arylpyrrole-2-aldimines

  摘要：

  A series of 17N-arylpyrrole-2-aldimine ligands has been synthesized by condensation of pyrrole-2-carboxaldehyde and substituted anilines. All CuL2 complexes are square, whereas NiL2 compounds are square, tetrahedral or eventually present a square half arrow right over half arrow left tetrahedral equilibrium. Attempts of chemical oxidation have shown the existence of nickel(III) and copper(III) in solution.

  DOI：

  10.1016/s0277-5387(00)80241-7