o-Aethylbutyrophenon | 35028-12-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: o-Aethylbutyrophenon
• 英文别名: 1-(2-ethyl-phenyl)-butan-1-one；1-(2-Aethyl-phenyl)-butan-1-on；2'-Ethylbutyrophenone；1-(2-ethylphenyl)butan-1-one
• CAS: 35028-12-7
• 化学式: C₁₂H₁₆O
• 分子量: 176.258
• InChiKey: VLAHAZODQDXBFB-UHFFFAOYSA-N

物化性质

• 沸点：
  123-128 °C(Press: 12 Torr)
• 密度：
  0.943±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  o-Aethylbutyrophenon 在 potassium permanganate 、 selenium(IV) oxide 、 异丙醇 作用下， 生成 2-乙基萘-1,4-二酮
  参考文献：
  名称：

  Weygand et al., Chemische Berichte, 1957, vol. 90, p. 1879,1890

  摘要：

  DOI：
• 作为产物：
  描述：

  乙基苯 、 丁酰氯 生成 o-Aethylbutyrophenon
  参考文献：
  名称：

  YULDASHEV X. YU., ZH. ORGAN. XIMII, 1978, 14, HO 1, 113-116

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING CYCLOHEXYL ALKYL KETONES
  申请人：Nishiuchi Junya

  公开号：US20120178970A1

  公开（公告）日：2012-07-12

  Provided is an industrially superior method for producing cyclohexyl alkyl ketones, which solves the problems in process reduction and in disposal of wastes such as metals. An aromatic ketone represented by a formula (1) is nuclear-hydrogenated with pressurized hydrogen and in the presence of a solvent at a temperature of from 20 to 120° C., in the presence of a catalyst that carries from 0.1 to 20% by weight of a ruthenium atom on the carrier, thereby producing a cyclohexyl alkyl ketone represented by a formula (2): provided that, in the formula (2), n indicates an integer of from 1 to 3; R represents a hydroxyl group, a cyclohexyl group, an alkyl group having from 1 to 4 carbon atoms, or an acyl group having from 1 to 4 carbon atoms

  提供了一种在工业上优越的生产环己基烷基酮的方法，解决了在过程减少和处理废物（如金属）方面的问题。通过在20至120°C的温度下，在有溶剂存在的情况下使用加压氢气进行核氢化，存在携带从0.1到20%重量的钌原子的催化剂，从而产生一个由式（2）表示的环己基烷基酮：其中，在式（2）中，n表示1到3之间的整数；R代表一个羟基、一个环己基、一个含有1至4个碳原子的烷基或一个含有1至4个碳原子的酰基。
• Holographic recording medium
  申请人：Kabushiki Kaisha Toshiba

  公开号：EP1939686A1

  公开（公告）日：2008-07-02

  A holographic recording medium (12) is provided, which includes a recording layer (19) comprising a three-dimensional cross-linking polymer matrix, a radical polymeric compound, and a photo-radical polymerization initiator. The three-dimensional cross-linking polymer matrix is represented by the following general formula (1): where m is an integer ranging from 3 to 16.

  提供了一种全息记录介质（12），它包括一个记录层（19），记录层由三维交联聚合物基体、自由基聚合物化合物和光致发光聚合引发剂组成。三维交联聚合物基质由以下通式（1）表示： 其中 m 为 3 至 16 的整数。
• Ink composition and inkjet recording method using the same
  申请人：Fujifilm Corporation

  公开号：EP2053095A2

  公开（公告）日：2009-04-29

  The invention provides an ink composition including (i) a sensitizing dye having a polymerizable group as a substituent, (ii) a polymerization initiator and (iii) a polymerizable compound having an ethylenically unsaturated bond. The invention also provides an inkjet recording method and a polymerizable compound useful as a sensitizing dye. The sensitizing dye (i) is represented by Formula (I) or (II) below. In the formulae, X represents O, S, NRa, or NRb, n1 and n2 each represent 0 or 1, Ra, Rb, and R1 to R18 each represent a hydrogen atom or a monovalent substituent, and one polymerizable group is present in the molecule.

  本发明提供了一种墨水组合物，包括(i)具有可聚合基团作为取代基的敏化染料，(ii)聚合引发剂和(iii)具有乙烯不饱和键的可聚合化合物。本发明还提供了一种喷墨记录方法和一种用作敏化染料的可聚合化合物。敏化染料(i)由下式(I)或(II)表示。式中，X代表O、S、NRa或NRb，n1和n2各自代表0或1，Ra、Rb和R1至R18各自代表氢原子或一价取代基，分子中存在一个可聚合基团。
• Beger, J.; Thielemann, C., Journal fur praktische Chemie (Leipzig 1954), 1981, vol. 323, # 1, p. 137 - 148
  作者：Beger, J.、Thielemann, C.

  DOI：——

  日期：——
• Holographic optical recording medium, manufacturing method thereof and holographic optical recording method
  申请人：Hayase Rumiko

  公开号：US20050068593A1

  公开（公告）日：2005-03-31

  Disclosed is a holographic optical recording medium comprising a recording layer having a skeleton structure represented by following general formula (A): where R 1 denotes an atomic group selected from the group consisting of a linear or branched alkylene group having 1 to 10 carbon atoms and an arylene group having 1 to 10 carbon atoms, it being possible for a halogen atom or an alkoxy group to be substituted in R 1 , and each of p and q is 0 or 1.