Bis(3,5-dimethylpyrazole-1-carbodithioato) Nickel(II) and Its Transformation to a Dinuclear Complex: Crystal Structure of [Ni<sub>2</sub>(μ-3,5-Me<sub>2</sub>Pz)<sub>2</sub>(L<sup>1</sup>)<sub>2</sub>] (L<sup>1</sup> = 3,5-dimethylpyrazole-1-carbodithioate)
作者:Sami Mukhopadhyay、Uday Mukhopadhyay、Thomas C. W. Mak、Debashis Ray
DOI:10.1021/ic000138i
日期:2001.2.1
The reaction of NiCl2. 6H(2)O with potentially bidentate N,S donor pyrazole-1-carbodithioate ligands produces four-coordinated diamagnetic (NiN2S2)-N-II complexes quantitatively. In solution Ni(L-1)(2) (L-1 = 3,5-dimethylpyrazole-1-carbodithioate) transforms to dimeric bis(3,5-dimethylpyrazole-1-carbodithioato) bis(mu -3,5-dimethylpyrazolato)dinickel(II), [Ni-2(mu -3,5-Me(2)Pz)(2)(L-1)(2)] (1).