[8-(2-tosylaminobenzylideneimino)quinolinato]copper acetate | 221083-36-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [8-(2-tosylaminobenzylideneimino)quinolinato]copper acetate
• 英文别名: (2-tosylaminato-N-(8-quinolyl)benzylaldimine)copper acetate
• CAS: 221083-36-9
• 化学式: C₂₅H₂₁CuN₃O₄S
• 分子量: 523.071
• InChiKey: NQWRROIHRZVBKO-BYEGLACWSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  8-(2-tosylaminobenzilideneimino)quinoline 、 copper diacetate 以 乙醇 为溶剂， 生成 [8-(2-tosylaminobenzylideneimino)quinolinato]copper acetate
  参考文献：
  名称：

  Uraev; Nivorozhkin; Korshunov, Russian Journal of Coordination Chemistry, 1999, vol. 25, # 1, p. 74 - 75

  摘要：

  DOI：

文献信息

• Synthesis and EXAFS investigation of azomethynic copper metallochelates with an N,S,O ligand environment
  作者：A.I Uraev、V.G Vlasenko、B.I Kharisov、L.M Blanco、A.T Shuvaev、I.S Vasilchenko、A.D Garnovskii、N.V Elizondo

  DOI：10.1016/s0277-5387(00)00572-6

  日期：2000.11

  Neutral copper complex of different composition (CuL21 and CuL (OAc)-O-2) and structure were obtained by coupling the 1-phenyl(isopropyl)-3-methyl-4-(N-substituted)aldimino-5-oxy(thio,seleno)pyrazoles (HL1), and 2-hydroxy(tosylamino)-N-(8-quinolyl)benzaldimine (HL2) with copper(II) acetate. According to X-ray structural data, the CuL21 complexes possess the pseudotetrahedral structure, and the (CuLOAc)-O-2 complexes, the square-pyramidal one. The complexes were studied by EXAFS spectroscopy. EXAFS spectral data on the nearest ligand environment show a good correlation with the X-ray structural results. (C) 2000 Elsevier Science B.V. All rights reserved.
• Vasil'chenko; Antsyshkina; Burlov, Russian Journal of Inorganic Chemistry, 1999, vol. 44, # 8, p. 1205 - 1213
  作者：Vasil'chenko、Antsyshkina、Burlov、Sadikov、Uraev、Nivorozhkin、Garnovskii、Sergienko、Kurbatov、Korshunov、Garnovskii

  DOI：——

  日期：——