1-(hexyloxy)-4-isocyanobenzene | 178864-63-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(hexyloxy)-4-isocyanobenzene
• 英文别名: 1-Hexoxy-4-isocyanobenzene
• CAS: 178864-63-6
• 化学式: C₁₃H₁₇NO
• 分子量: 203.284
• InChiKey: ZBDJLDLTWQNWSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  13.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 1-(hexyloxy)-4-isocyanobenzene 以 丙酮 为溶剂， 反应 2.0h， 以99%的产率得到(((4-(hexyloxy)phenyl)-l4-azaneylidyne)methyl)gold(II) chloride
  参考文献：
  名称：

  液晶金（i）配合物的发光的可逆热模式控制†

  摘要：

  描述了设计成具有二聚体形式的棒状结构的液晶（LC）金配合物的合成和表征，并讨论了其光物理性质与聚集结构之间的关系。在凝聚相中，复合物的发光强度增强，这意味着复合物显示出聚集诱导的发射。凝结相中观察到的光致发光可归因于单体发射；然而，发光性能受到配合物聚集结构的强烈影响。演示了由LC和各向同性相之间的相变引起的发光的可逆“开-关”切换。此外，复合物1b表现出由聚集结构控制的热致变色光致发光；发光的颜色可以通过晶相和LC相之间的相变可逆地控制。这些LC金络合物显示出作为新型发光器件材料的潜在应用。

  DOI：

  10.1039/c3tc31973c
• 作为产物：
  描述：

  对氨基苯酚 在 potassium carbonate 、 对甲苯磺酸 、 二氯磷酸苯酯 、 三乙胺 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 50.0h， 生成 1-(hexyloxy)-4-isocyanobenzene
  参考文献：
  名称：

  MARINE SESSILE ORGANISM-REPELLING COMPOSITION

  摘要：

  一个由以下公式表示的化合物：其中R从苯甲基、C3-11烷基、C3-11烯基、C2-9支链烯基、C3-9支链烷基和—CH2OAc组成的群体中选择。

  公开号：

  US20180072657A1

文献信息

• MARINE PERIPHYTON REPELLENT COMPOSITION
  申请人：Basseru Chemical Co., Ltd.

  公开号：EP3309145A1

  公开（公告）日：2018-04-18

  A compound represented by the formula below: wherein R is selected from the group consisting of benzyl, C3-11 alkyl, C3-11 alkenyl, C2-9 branched alkenyl, C3-9 branched alkyl, and -CH2OAc.

  下式所代表的化合物： 其中 R 选自由苄基、C3-11 烷基、C3-11 烯基、C2-9 支链烯基、C3-9 支链烷基和 -CH2OAc 组成的组。
• Liquid-Crystalline Mono- and Dinuclear (Perhalophenyl)gold(I) Isocyanide Complexes
  作者：Rocio Bayón、Silverio Coco、Pablo Espinet、César Fernández-Mayordomo、José M. Martín-Alvarez

  DOI：10.1021/ic960917s

  日期：1997.5.1

  Rodlike gold(I) and gold(III) complexes [AuR(C drop N(C6H4)(m)OCnH2n+1-p)] (m = 1, n = 10, R = C6F5; m = 2, n = 4, 6, 8, 10, 12, R = C6F5, C6F4Br-o, C6F4Br-p), [(mu-4,4'-C6F4C6F4)AuC drop N(C6H4)(m)OCnH2n+1}(2)] (m = 1, 2; n = 4, 6, 8, 10, 12), [AuRI2(C drop NC6H4C6H4OCnH2+1-p)] (R = C6F5, n = 8; R = C6F4Br-o, n = 10), and [(mu-4,4'-C6F4C6F4)AuX2C drop N(C6H4)(m)OCmH2n+1}(2)] (m = 1, 2; n = 4, 6, 8, 10, 12) have been prepared and their liquid crystal behavior has been studied. The gold(III) compounds are not mesomorphic, but all the perhalo-gold(I) derivatives described are liquid crystals except the phenyl isocyanide gold(I) derivative [Au(C6F5)(C drop NC6H4-OC10H21-p)]. The mononuclear derivatives show only a nematic (N) phase when the isocyanides have a short tail (n = 4), N and smectic A phases (S-A) when the isocyanides have an intermediate tail (n = 6, 8), and only S-A phases for longer chains. Their thermal stability is high, even in the isotropic state. The variation in transition temperatures is as follows: C6F4Br-p greater than or equal to C6F5 > C6F4Br-o when n less than or equal to 6 and C6F4Br-p > C6F4Br-o > C6F5 for n greater than or equal to 8. This behavior is understood on the basis of electronic and steric factors. The dinuclear compounds [(mu-4,4'-C6F4C6F4)AuC drop N(C6H4)(m)OCnH2n+1}(2) display only N mesophases and all the biphenylisocyanide derivatives and phenyl isocyanide compounds with n less than or equal to 6 undergo some decomposition upon reaching the clearing point to the isotropic state.
• Compound ,Composition And Thin Film
  申请人：Takahashi Makoto

  公开号：US20080064879A1

  公开（公告）日：2008-03-13

  A liquid-crystalline compound of the following formula: wherein Y 11 , Y 12 and Y 13 are methine or N; L 1 , L 2 and L 3 are single bond or divalent group; H 1 , H 2 and H 3 are formula (DI-A) or (DI-B); YA 1 , YA 2 , YB 1 and YB 2 are methine or N; XA and XB are O, S, etc.; R 1 , R 2 and R 3 are -(-L 21 -Q 2 ) n1 -L 22 -L 23 -Q 1 ; L 21 is single bond or divalent group; Q 2 is cyclic divalent group; n1 is 0-4; L 22 is —O—, —O—CO—, etc; L 23 is —O—, —S—, etc.; Q 1 is polymerizable group or H.
• Retardation Plate, Elliptically Polarizing Plate and Liquid Crystal Display
  申请人：Nishikawa Hideyuki

  公开号：US20080193679A1

  公开（公告）日：2008-08-14

  A retardation plate comprising at least one optically anisotropic layer, wherein at least one of said optically anisotropic layers is formed from a composition containing a liquid crystalline compound represented by the following formula: wherein Y 11 , Y 12 and Y 13 are methine or N; L 1 , L 2 and L 3 are single bond or divalent group; H 1 , H 2 and H 3 are formula (DI-A) or (DI-B); YA 1 , YA 2 , YB 1 and YB 2 are methine or N; XA and XB are O, S, etc.; R 1 , R 2 and R 3 are -(-L 21 -Q 2 ) n1 -L 22 -L 23 -Q 1 ; L 21 is single bond or divalent group; Q 2 is cyclic divalent group; n1 is 0 - 4; L 22 is —O—, —O—CO—, etc; L 23 is —O—, —S—, etc.; Q 1 is polymerizable group or H.
• Compound, composition and thin film
  申请人：Takahashi Makoto

  公开号：US20100222594A1

  公开（公告）日：2010-09-02

  A compound represented by the following formula (DII): wherein Y 31 , Y 32 and Y 33 each independently represents a methine group or a nitrogen atom; R 31 , R 32 and R 33 each independently represents the following formula (DII-R):