N-allylquinolinium chloride | 31663-59-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: N-allylquinolinium chloride
• 英文别名: 1-prop-2-enylquinolin-1-ium;chloride
• CAS: 31663-59-9
• 化学式: C₁₂H₁₂N*Cl
• 分子量: 205.687
• InChiKey: FEJUUNUDNXFOOZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.68
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  3.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-allylquinolinium chloride 以 乙醇 、 苯 为溶剂， 生成 N-allylquinolinium CuCl3 N-allylquinoline
  参考文献：
  名称：

  摘要：

  The crystals of [C9H7N(C3H5)](2)(CuCl4)-Cl-II (IV) were obtained through ac electrochemical synthesis using CuCl2. 2H(2)O, N-allylquinolinium chloride, and copper electrodes in an ethanol-benzene medium. These crystals transformed with time into crystals of the [C9H7N(C(3)H5)j1Cu(II)Cl(3)(C9H7N)] complex (V). When tin(II) chloride was added to the initial reagents, the [C9H7N(C3H5)]Cu-2(I) Cl-3 Complex (VI) was obtained. The X-ray diffraction analysis (DARCh-I autodiffractometer, MoKalpha radiation, Zr filter) indicated that complexes IV and V crystallize in the triclinic system: space group P (1) over bar; for IV, a = 12.817(4), b = 10.435(3), c = 9.606(3) Angstrom, alpha = 97.94(2)degrees, beta = 107.28(2)degrees, gamma = 95.99(2)degrees, V = 1200.6(6) Angstrom (3), Z = 2; for V, a = 16.992(5), b = 8.243(2), c = 7.345(3) Angstrom, alpha = 91.89(3)degrees, beta = 91.19(3)degrees, gamma = 88.18(3)degrees, V = 1027.5(6) Angstrom (3), Z = 2. Crystals VI are monoclinic, space group P2(1)/n, a = 13.578(5), b = 15.079(4), c = 6.953(4) Angstrom, beta = 105.08(4)degrees, V = 1370.6(10) Angstrom (3), Z = 4. Structures IV-VI consist of N-allylquinolinium cations and different anions: isolated [CuCl4](2-) tetrahedrons (IV), [C9H7NCuCl3](-) tetrahedrons (V) containing a quinoline molecule, and a polymer chain ([Cu-4(I) Cl-6](2-))(n) (VI) in which two independent metal atoms have trigonal-pyramidal and planar-trigonal environments. The C=C bond of the allyl group is not involved in cooordination with the Cu(I) atom.

  DOI：

  10.1023/a:1013065129446

文献信息

• METHOD FOR MANUFACTURING AN EPOXY COMPOUND AND METHOD FOR EPOXIDIZING A CARBON-CARBON DOUBLE BOND
  申请人：Takumi Kiyoshi

  公开号：US20120108830A1

  公开（公告）日：2012-05-03

  The present invention provides a method for producing an epoxy compound, comprising oxidizing a carbon-carbon double bond of an organic compound by hydrogen peroxide in the presence of a neutral inorganic salt and a mixed catalyst of a tungsten compound (a), at least one phosphorus compound selected from the group consisting of phosphoric acids, phosphonic acids, and salts thereof (b) and a surfactant (c), and an epoxidizing method comprising oxidizing a carbon-carbon double bond by hydrogen peroxide in the presence of the catalyst and the neutral inorganic salt.

  本发明提供了一种生产环氧化合物的方法，包括在中性无机盐和钨化合物（a）、磷酸、膦酸及其盐（b）和表面活性剂（c）的混合催化剂存在下，通过过氧化氢氧化有机化合物的碳-碳双键，以及一种环氧化方法，包括在催化剂和中性无机盐存在下，通过过氧化氢氧化碳-碳双键。
• METHOD OF PRODUCING EPOXY COMPOUNDS
  申请人：Uchida Hiroshi

  公开号：US20110263882A1

  公开（公告）日：2011-10-27

  Provided is a method of efficiently producing an epoxy compound from an allyl ether having an aromatic ring under mild conditions by using hydrogen peroxide as an oxidizing agent without using an organic solvent. The method of producing an epoxy compound comprises reacting an allyl ether having an aromatic ring with hydrogen peroxide to epoxidize a carbon-carbon double bond of an allyl group to thereby produce a corresponding epoxy compound having an aromatic ring, wherein water only is used as a solvent without using an organic solvent, and a tungsten compound, and a tertiary amine and/or a quaternary ammonium salt, are used as a reaction catalyst.

  提供了一种在温和条件下使用过氧化氢作为氧化剂，而无需使用有机溶剂，从具有芳香环的烯丙基醚高效生产环氧化合物的方法。生产环氧化合物的方法包括将具有芳香环的烯丙基醚与过氧化氢反应，使烯丙基团的碳-碳双键环氧化，从而产生具有芳香环的相应环氧化合物，其中仅使用水作为溶剂，不使用有机溶剂，并且使用钨化合物、三级胺和/或季铵盐作为反应催化剂。
• EPOXY COMPOUND PRODUCTION METHOD
  申请人：Showa Denko K.K.

  公开号：EP2383264A1

  公开（公告）日：2011-11-02

  Provided is a method of efficiently producing an epoxy compound from an allyl ether having an aromatic ring under mild conditions by using hydrogen peroxide as an oxidizing agent without using an organic solvent. The method of producing an epoxy compound comprises reacting an allyl ether having an aromatic ring with hydrogen peroxide to epoxidize a carbon-carbon double bond of an allyl group to thereby produce a corresponding epoxy compound having an aromatic ring, wherein water only is used as a solvent without using an organic solvent, and a tungsten compound, and a tertiary amine and/or a quaternary ammonium salt, are used as a reaction catalyst.

  本发明提供了一种在不使用有机溶剂的情况下，利用过氧化氢作为氧化剂，在温和条件下从具有芳香环的烯丙基醚中高效生产环氧化合物的方法。生产环氧化合物的方法包括使具有芳香环的烯丙基醚与过氧化氢反应，使烯丙基的碳碳双键环氧化，从而生成相应的具有芳香环的环氧化合物，其中只用水作为溶剂而不使用有机溶剂，钨化合物和叔胺和/或季铵盐作为反应催化剂。
• PREVENTION OF SLUDGE FORMATION DURING ACIDIZING PROCEDURES
  申请人：Ecolab USA Inc.

  公开号：EP2970755A1

  公开（公告）日：2016-01-20
• QUATERNARY AMINE FORMULATIONS AND USES THEREOF
  申请人：Vertellus Holdings LLC

  公开号：EP3554233A1

  公开（公告）日：2019-10-23