2,4,6-triethylphenacyl benzoate | 1220167-00-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,4,6-triethylphenacyl benzoate
• CAS: 1220167-00-9
• 化学式: C₂₁H₂₄O₃
• 分子量: 324.42
• InChiKey: UXXUAGLJYBXVCY-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2,4,6-triethylphenacyl benzoate 以 甲醇 为溶剂， 生成 [(7S,8R)-3,5-diethyl-7-hydroxy-8-methyl-7-bicyclo[4.2.0]octa-1,3,5-trienyl]methyl benzoate 、 [(7S,8S)-3,5-diethyl-7-hydroxy-8-methyl-7-bicyclo[4.2.0]octa-1,3,5-trienyl]methyl benzoate
  参考文献：
  名称：

  Unique solvent effect on photochemistry of ortho-alkylphenacyl benzoates

  摘要：

  Photolysis of 2,4,6-trialkylphenacyl benzoates gives not only the corresponding indanones and benzoic acid, but also the corresponding benzocyclobutenols (CBs), which are also detected in the photolysis of mono-alkylphenacyl benzoates for the first time. The product selectivity was heavily dependent upon solvents and o-alkyl group. H-bonding acceptor solvents strongly favor the formation of the CB. As the size of the o-alkyl group increases, the relative amount of the CB increases. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.01.046