| 866496-07-3

• CAS: 866496-07-3
• 化学式: C₁₈H₂₃ClN₂PdS₂
• 分子量: 473.399
• InChiKey: HFAWGFBQXATIKI-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  [3-(Piperidine-1-carbothioyl)-phenyl]-piperidin-1-yl-methanethione 、 potassium tetrachloropalladate(II) 生成
  参考文献：
  名称：

  Luminescence Study of Thioamide-based Pincer Palladium Complexes in Poly(vinylpyrrolidone) Matrix

  摘要：

  含有二级硫代酰胺单元的钳形钯复合物加入聚乙烯吡咯烷酮基质后，在室温下显示出强烈的磷光；混合薄膜在暴露于挥发性有机化合物时显示出可逆的发光切换。

  DOI：

  10.1246/cl.2010.385

文献信息

• Luminescent palladium complexes containing thioamide-based SCS pincer ligands
  作者：Michinori Akaiwa、Takaki Kanbara、Hiroki Fukumoto、Takakazu Yamamoto

  DOI：10.1016/j.jorganchem.2005.06.026

  日期：2005.9

  Thioamide-based tridentate ligands, 1,3-benzenedicarbothioamides (1a-c), were used to afford pincer palladium(II) complexes (Pd(1-H)Cl, 2a-c) with eta(3)-S,C,S type coordination. The complexes exhibit strong emission in a glassy frozen state as well as in the solid state. The decay lifetime of the emission from the complexes is in a range of 8-9 x 10(-5) s, which is indicative of phosphorescent emission. (c) 2005 Elsevier B.V. All rights reserved.