Mn(2,2'-bipyridine)2(3,5-diisopropylsalicylic acid)2 | 1265633-46-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Mn(2,2'-bipyridine)2(3,5-diisopropylsalicylic acid)2
• CAS: 1265633-46-2
• 化学式: C₄₆H₅₀MnN₄O₆
• 分子量: 809.864
• InChiKey: PKEXULGHPRYKPE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (Mn(CH3COO)(2,2'-bipyridine)2)(ClO4)*H2O 、 3,5-二异丙基邻羟基苯甲酸 以 甲醇 为溶剂， 以80%的产率得到Mn(2,2'-bipyridine)2(3,5-diisopropylsalicylic acid)2
  参考文献：
  名称：

  Synthesis, spectral characterization, and single crystal X-ray structures of a series of manganese-2,2′-bipyridine complexes derived from substituted aromatic carboxylic acids

  摘要：

  Reaction of [Mn(2,2'-bpy)(2)(OAc)](ClO4)(H2O) with a series of aromatic carboxylic acids yields new Mn(II)carboxylates [Mn(2,2'-bpy)(2)(L)](ClO4)}(2) (1-3), [Mn(2,2'-bpy)(2)(L)(2)] (4-5) and [Mn(2,2'-bpy)(2)(L)(-H2O)]( ClO4) (6) (L = 2-aminobenzoate (2-aba) (1), 4-hydroxybenzoate (4-hba) (2), thiophene-2-carboxylate (2-tca) (3), 2-hydroxynapthoate (2-hnapa) (4), 3,5-diisopropylsalicylic acid (dipsa) (5), 2,4, 6-triisopropylbenzoate (tipba) (6)). The new compounds have been characterized with the aid of elemental analysis, spectroscopy, and single-crystal X-ray diffraction studies. Compounds 1-3, which have been synthesized from less bulky carboxylic acids, are dimeric in the solid-state. Compounds 4-6, which are derived from more bulkier aromaric carboxylic acids, exist as monomeric complexes. In the case of 6, where very bulky 2,4,6-triisopropyl benzoic acid is used as the starting material, only one carboxylate ligand binds to the metal, resulting in a cationic complex. Interestingly in all the six complexes, the C-H hydrogen atoms of the 2,2'-bpy ligands are involved in extensive hydrogen bonding with the carboxylate oxygen atoms of the adjacent molecules and hence form non-covalent 1-D or 2-D aggregates in the solid state. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.09.040