Salzsaure Kohlendioxyd | 108480-31-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Salzsaure Kohlendioxyd
• CAS: 108480-31-5
• 化学式: CO₂*ClH
• 分子量: 80.4707
• InChiKey: NUGKZPIIWZOBBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.16
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  盐酸 、 二氧化碳 以 gaseous matrix 为溶剂， 生成 Salzsaure Kohlendioxyd
  参考文献：
  名称：

  The infrared spectroscopy and dynamics of OCO–HCl and SCO–HCl: An example of mode specific intermolecular energy transfer

  摘要：

  Optothermal near infrared laser spectroscopy has been used to study the OCO–HCl and SCO–HCl complexes by exciting the H–Cl stretch using an F-center laser. In both cases, the two isotopic forms associated with H35Cl and H37Cl have been observed. All of the observed spectra are consistent with and analyzed in terms of a linear structure. Vibrational predissociation is observed to be abnormally fast in the OCO–HCl complex, considering the rather weak coupling between the intermolecular degrees of freedom and the H–Cl stretch suggested by the small vibrational frequency shift associated with complex formation. Comparisons are made between the two systems studied here that indicate that this anomalous rate is due to a near resonance between the energy available to the fragments after the photodissociation of the complex and the asymmetric stretch of the CO2 fragment.

  DOI：

  10.1063/1.472636