tris[aqua-diphenyl-μ2-(2,5-pyridinedicarboxylato-O,O',N)tin] | 849427-19-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tris[aqua-diphenyl-μ2-(2,5-pyridinedicarboxylato-O,O',N)tin]
• CAS: 849427-19-6
• 化学式: C₅₇H₄₅N₃O₁₅Sn₃
• 分子量: 1368.13
• InChiKey: GBLCFVNZIWWOSS-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tris[aqua-diphenyl-μ2-(2,5-pyridinedicarboxylato-O,O',N)tin] 、 二甲基亚砜 以 二甲基亚砜 为溶剂， 生成 [[Ph2Sn(2,5-pyridinedicarboxylato)(dimethyl sulfoxide)]3*5(dimethyl sulfoxide)]
  参考文献：
  名称：

  Self-Assembly of Diorganotin(IV) Oxides (R = Me, nBu, Ph) and 2,5-Pyridinedicarboxylic Acid to Polymeric and Trinuclear Macrocyclic Hybrids with Porous Solid-State Structures:  Influence of Substituents and Solvent on the Supramolecular Structure

  摘要：

  2,5-Pyridinedicarboxylic acid has been reacted with three different diorganotin(IV) oxides (R = Me, nBu, Ph) to study the molecular and supramolecular structures of the resulting diorganotin(IV) 2,5-pyridinedicarboxylates. It has been found that coordinating solvent molecules can change the supramolecular structure completely. The molecular structures found are either polymeric (zigzag) or cyclotrimeric; the supramolecular arrangements include (i) systems having only loosely bound discrete molecules (van der Waals contacts), (ii) systems having a 2D or 3D hydrogen-bonded structure, and (iii) systems having a 3D polymeric coordination structure. Channels or cavities are formed in several cases. For a particular case, evidence has been provided that molecular aggregation to capsules through hydrogen bonding interactions is possible in solution.

  DOI：

  10.1021/ja0437095
• 作为产物：
  描述：

  2,5-pyridinedicarboxylic acid 、 二苯基氧化锡 以 乙醇 、 甲苯 为溶剂， 以81%的产率得到tris[aqua-diphenyl-μ2-(2,5-pyridinedicarboxylato-O,O',N)tin]
  参考文献：
  名称：

  Self-Assembly of Diorganotin(IV) Oxides (R = Me, nBu, Ph) and 2,5-Pyridinedicarboxylic Acid to Polymeric and Trinuclear Macrocyclic Hybrids with Porous Solid-State Structures:  Influence of Substituents and Solvent on the Supramolecular Structure

  摘要：

  2,5-Pyridinedicarboxylic acid has been reacted with three different diorganotin(IV) oxides (R = Me, nBu, Ph) to study the molecular and supramolecular structures of the resulting diorganotin(IV) 2,5-pyridinedicarboxylates. It has been found that coordinating solvent molecules can change the supramolecular structure completely. The molecular structures found are either polymeric (zigzag) or cyclotrimeric; the supramolecular arrangements include (i) systems having only loosely bound discrete molecules (van der Waals contacts), (ii) systems having a 2D or 3D hydrogen-bonded structure, and (iii) systems having a 3D polymeric coordination structure. Channels or cavities are formed in several cases. For a particular case, evidence has been provided that molecular aggregation to capsules through hydrogen bonding interactions is possible in solution.

  DOI：

  10.1021/ja0437095