bis(((s)-2-(4-bromo-2,3,5,6-tetramethylphenyl)-9-mesityl-1,10-phenanthrolin-3-yl)ethynyl)bis(triethyl-l5-phosphaneyl)platinum | 856659-03-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: bis(((s)-2-(4-bromo-2,3,5,6-tetramethylphenyl)-9-mesityl-1,10-phenanthrolin-3-yl)ethynyl)bis(triethyl-l5-phosphaneyl)platinum
• CAS: 856659-03-5
• 化学式: C₇₈H₈₆Br₂N₄P₂Pt
• 分子量: 1496.4
• InChiKey: CBQHVRRMZRRZJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  顺-二氯双(三乙基膦)铂(II) 、 2-(4-bromo-2,3,5,6-tetramethylphenyl)-3-ethynyl-9-mesityl-1,10-phenanthroline 在 O₂ 、 CuCl 、 triethylamine 作用下， 生成 bis(((s)-2-(4-bromo-2,3,5,6-tetramethylphenyl)-9-mesityl-1,10-phenanthrolin-3-yl)ethynyl)bis(triethyl-l5-phosphaneyl)platinum
  参考文献：
  名称：

  Metal-Driven and Covalent Synthesis of Supramolecular Grids from Racks:  A Convergent Approach to Heterometallic and Heteroleptic Nanostructures

  摘要：

  Supramolecular nanogrids were prepared from dynamic supramolecular racks through the coupling of terminal alkynes using either a covalent (with CuCl/O-2) or a coordinative (with [trans-(PEt3)(2)PtCl2]) approach. Because of the rapid equilibration of the racks (as tested by exchange reactions), oligomeric adducts potentially formed in the coupling process will selectively furnish the nanogrids through an entropically driven self-repair mechanism. To ascertain the structural assignment, the nanogrids were also synthesized by an independent strategy.

  DOI：

  10.1021/ic050088n