Ni(II)(N,N'-bis(2-aminoethyl)ethane-1,2-diamine)(cis-μ2-Ni(CN)4) | 192060-80-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Ni(II)(N,N'-bis(2-aminoethyl)ethane-1,2-diamine)(cis-μ2-Ni(CN)4)
• CAS: 192060-80-3；1267597-15-8
• 化学式: C₁₀H₁₈N₈Ni₂
• 分子量: 367.687
• InChiKey: NYBOKLPUJJBRQU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 potassium tetracyanidonickellate(II) monohydrate 、 三乙烯四胺 在 Ni(OH)2 作用下， 以 水 为溶剂， 生成 Ni(II)(N,N'-bis(2-aminoethyl)ethane-1,2-diamine)(cis-μ2-Ni(CN)4)
  参考文献：
  名称：

  Heterobimetallic assemblies of Ni(II) complexes with a tetradentate amine ligand and diamagnetic cyanidometallates

  摘要：

  Syntheses and crystal structures of nickel(II) complexes containing teta (teta = N,N'-bis(2-aminoethyl)ethane-1,2-diamine) as a tetradentate blocking ligand and cyanidometallic bridging complexes are described. The complexes [Ni(teta)(cis-mu(2)-Ni(CN)(4))] (1) and [{Ni(teta)}(3)(mu(6)-Co(CN)(6))] (ClO4)(3) (2) exhibit a 1D-polymeric structure whereas the heterometallic trinuclear complex [Ni(teta)(mu(1)-Ag(CN)(2))(2)] (3) forms a unique network. The weak antiferromagnetic exchange was found in polymeric species 1 and 2 by analyzing the magnetic data with several models in which either only susceptibility was treated or simultaneous fitting of temperature and magnetic field dependences of the magnetization was applied using the finite-size closed ring approach. Moreover, an effect of the zero-field splitting phenomenon (ZFS) was considered for 2 by advanced modeling of magnetic properties for varying axial ZFS parameter/isotropic exchange (D/J) ratios. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.11.028