Acetic acid (2R,3S,4R,5R,6S)-2-acetoxymethyl-5-acetylamino-3-((2S,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-6-((2S,3S,4S,5R,6R)-2,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester | 91078-46-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Acetic acid (2R,3S,4R,5R,6S)-2-acetoxymethyl-5-acetylamino-3-((2S,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-6-((2S,3S,4S,5R,6R)-2,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester
• CAS: 91078-46-5
• 化学式: C₆₀H₇₁NO₂₂
• 分子量: 1158.22
• InChiKey: PGURAUMSMXMOIG-VXGHYMRNSA-N

反应信息

• 作为反应物：
  描述：

  Acetic acid (2R,3S,4R,5R,6S)-2-acetoxymethyl-5-acetylamino-3-((2S,3R,4S,5S,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-6-((2S,3S,4S,5R,6R)-2,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester 在 sodium methylate 作用下， 以 甲醇 为溶剂， 生成 N-[(2S,3R,4R,5S,6R)-4-Hydroxy-6-hydroxymethyl-5-((2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-2-((2S,3S,4S,5R,6R)-2,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3-yl]-acetamide
  参考文献：
  名称：

  糖蛋白复杂类型的糖链的线性四糖单元的合成。

  摘要：

  DOI：

  10.1016/0008-6215(84)85120-4