12-(4-methoxyphenyl)-5H,7H-pyrido[2,3-b:6,5-b']diindole | 1415641-42-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 12-(4-methoxyphenyl)-5H,7H-pyrido[2,3-b:6,5-b']diindole
• 英文别名: 12-(4-methoxyphenyl)-5,7-dihydropyrido[2,3-b:6,5-b']diindole；2-(4-Methoxyphenyl)-10,12,14-triazapentacyclo[11.7.0.03,11.04,9.015,20]icosa-1(13),2,4,6,8,11,15,17,19-nonaene
• CAS: 1415641-42-7
• 化学式: C₂₄H₁₇N₃O
• 分子量: 363.418
• InChiKey: OQDRNOIEIHDMJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.03
• 重原子数：
  28.0
• 可旋转键数：
  2.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  53.7
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  溴苯 、 12-(4-methoxyphenyl)-5H,7H-pyrido[2,3-b:6,5-b']diindole 在 potassium phosphate 、 copper(l) iodide 、 1,10-菲罗啉 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 48.0h， 生成 2-(4-Methoxyphenyl)-10-phenyl-14-(6-phenylpyridin-2-yl)-10,12,14-triazapentacyclo[11.7.0.03,11.04,9.015,20]icosa-1(13),2,4,6,8,11,15,17,19-nonaene
  参考文献：
  名称：

  LIGHT-EMITTING DEVICE

  摘要：

  Provided are an organometallic compound, a light-emitting device including the organometallic compound, and an electronic apparatus including the light-emitting device. The light-emitting device includes a first electrode, a second electrode facing the first electrode, and an interlayer disposed between the first electrode and the second electrode. The interlayer includes an emission layer. The emission layer includes a first compound which is the organometallic compound; and a second compound, a third compound, a fourth compound, or any combination thereof. The first compound, the second compound, the third compound, and the fourth compound are different from one another.

  公开号：

  US20220310942A1
• 作为产物：
  描述：

  2-ethoxy-3-(4-methoxybenzylidene)indoleninium tetrafluoroborate 在 sodium ethanolate 、 一水合肼 作用下， 以 乙醇 为溶剂， 以23%的产率得到12-(4-methoxyphenyl)-5H,7H-pyrido[2,3-b:6,5-b']diindole
  参考文献：
  名称：

  Formation of the fused system 5H,7H-pyrido[2,3-b:6,5-b′]diindole from 3-arylidene-2-ethoxyindolenines and hydrazine hydrate

  摘要：

  从适当的 3-芳基-2-乙氧基吲哚和水合肼中获得了三种 12-芳基-5H,7H-吡啶并[2,3-b:6,5-b′]二吲哚（Ar = Ph、4-BrC6H4 和 4-MeOC6H4）。

  DOI：

  10.1007/s11172-012-0045-2

文献信息

• FeCl3-catalyzed sequential cyclization for the construction of 12-aryl 5,7-dihydropyrido[2,3-b:6,5-b']diindoles
  作者：Xiaoqian Chen、Lin Li、Changfeng Wan、Jin-Biao Liu

  DOI：10.1016/j.tetlet.2020.152334

  日期：2020.9

  A facile approach to prepare 12-aryl 5,7-dihydropyrido[2,3-b:6,5-b']diindoles via tandem cyclizations is described. FeCl3 is used as the catalyst for the reaction between o-aminophenylacetonitriles and aromatic aldehydes, generating 5,7-dihydropyrido[2,3-b:6,5-b']diindoles derivatives in moderate to high yields. (C) 2020 Elsevier Ltd. All rights reserved.