| 1381768-34-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1381768-34-8
• 化学式: C₈₂H₄₈B₂O₁₂
• 分子量: 1246.9
• InChiKey: RHXFCWGVDWZNHQ-MTITUFFHSA-N

反应信息

• 作为产物：
  描述：

  联硼酸频那醇酯 、 4,11,15,30-tetrakis(tert-butylperoxy)-1,2-dihydroxy-1,2,4,11,15,30-hexahydro[60]fullerene 以 二氯甲烷 为溶剂， 反应 0.5h， 以46%的产率得到
  参考文献：
  名称：

  Facile preparation of fullerenyl boronic esters

  摘要：

  The fullerendiol C-60(OH)(2)(OOt-Bu)(4) 1 reacts with various arylboronic acids ArB(OH)(2) to form fullerene-containing boronic esters C-60(O2BAr)(OOt-Bu)(4) in up to 95% yield depending on the structure of aryl group. Bis(pinacolato)diboron (B(OCMe2)(2))(2) also reacts with 1 to form C-60(O2BB(OCMe2)(2))(OOt-Bu)(4). The bisboronic ester C-60(O)(O2BAr)(2)(OOt-Bu)(2) was also obtained starting from a tetrahydroxyl fullerene derivative C-60(O)(OH)(4)(OOt-Bu)(2). The fullerenyl boronic esters are moderately stable in air. Single crystal X-ray structure of C-60(O2BPh)(OOt-Bu)(4) was obtained. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.03.092