4-[7-(4-氨基苯氧基)庚氧基]苯胺 | 2519-77-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 4-[7-(4-氨基苯氧基)庚氧基]苯胺
• 英文名称: 4,4'-heptanediyldioxy-di-aniline
• 英文别名: 1,7-Bis-[4-amino-phenoxy)-heptan；4,4'-Heptandiyldioxy-di-anilin；1,7-bis(4-aminophenoxy)heptane；1.7-Bis-(4-amino-phenoxy)-heptan；Benzenamine, 4,4'-(1,7-heptanediylbis(oxy))bis-；4-[7-(4-aminophenoxy)heptoxy]aniline
• CAS: 2519-77-9
• 化学式: C₁₉H₂₆N₂O₂
• 分子量: 314.428
• InChiKey: JBXBSFFXAMVASC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  23
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2922299090

反应信息

• 作为反应物：
  描述：

  4-[7-(4-氨基苯氧基)庚氧基]苯胺 生成 1,7-bis-(4-acetylamino-phenoxy)-heptane
  参考文献：
  名称：

  Yang et al., Huaxue Xuebao/Acta Chimica Sinica, 1956, vol. 22, p. 472,474

  摘要：

  DOI：
• 作为产物：
  描述：

  4-(4-nitrophenoxy)butanoic acid 在 盐酸 、 乙醇 、 铁粉 作用下， 生成 4-[7-(4-氨基苯氧基)庚氧基]苯胺
  参考文献：
  名称：

  Yang et al., Huaxue Xuebao/Acta Chimica Sinica, 1956, vol. 22, p. 472,474

  摘要：

  DOI：

文献信息

• NOVEL DIAMINE, POLYAMIC ACID, AND POLYIMIDE
  申请人：NISSAN CHEMICAL INDUSTRIES. LTD.

  公开号：US20160264520A1

  公开（公告）日：2016-09-15

  To provide a novel diamine, and a polyimide precursor and a polyimide using it. A diamine represented by the formula (1): wherein each of X 1 and X 5 which are independent of each other, is a single bond or the like; each of X 2 and X 4 which are independent of each other, is —CH 2 — or the like; X 3 is a C 1-6 alkylene or the like; each of Y 1 and Y 2 which are independent of each other, is a single bond or the like; R is a C 1-20 linear, branched or cyclic hydrocarbon group; and a is 0 or 1).

  提供一种新颖的二胺，以及使用它的聚酰亚胺前体和聚酰亚胺。一种由式（1）表示的二胺：其中X1和X5中的每一个独立的，是单键或类似物；X2和X4中的每一个独立的，是—CH2—或类似物；X3是C1-6烷基或类似物；Y1和Y2中的每一个独立的，是单键或类似物；R是C1-20线性、支链或环烃基；a为0或1。
• Synthesis and solid-state structures of a macrocyclic receptor based on the 2,6-bis(2-anilinoethynyl)pyridine scaffold
  作者：Jeffrey M. Engle、Pushpinder S. Singh、Chris L. Vonnegut、Lev N. Zakharov、Darren W. Johnson、Michael M. Haley

  DOI：10.1039/c3ce42307g

  日期：——

  A fluorescent macrocyclic anion receptor based on the 2,6-bis(2-anilinoethynyl)pyridine scaffold has been synthesized to investigate the mechanism of fluorescence quenching in this class of compounds. X-ray crystallography reveals that the binding pocket of the receptor is a natural host to both H2O and HCl, accommodating either molecule in nearly identical environments. Our studies show that protonation, not collisional quenching, is responsible for the observed fluorescence quenching response.

  我们合成了一种基于 2,6-双（2-苯胺乙炔基）吡啶支架的荧光大环阴离子受体，以研究这类化合物的荧光淬灭机制。X 射线晶体学显示，受体的结合口袋是 H2O 和 HCl 的天然宿主，在几乎相同的环境中可容纳这两种分子。我们的研究表明，质子化作用而非碰撞淬灭作用是造成所观察到的荧光淬灭反应的原因。
• Liquid-Crystal Aligning Agent, Liquid-Crystal Alignment Film Comprising the Same, and Liquid-Crystal Element
  申请人：Tsutsui Kimiaki

  公开号：US20070224370A1

  公开（公告）日：2007-09-27

  It is to provide a liquid crystal aligning agent capable of forming a liquid crystal alignment film having favorable electrical characteristics, and excellent in the storage stability and the productivity. A liquid crystal aligning agent comprising at least one member selected from a polyamic acid obtained by polymerization of a diamine component with a tetracarboxylic dianhydride component, and a polyimide obtained by cyclodehydration of the polyamic acid, characterized in that the diamine component contains at least one of diamines represented by the following formula [1]: H 2 N-A-R—NH 2 [1] wherein A is a bivalent organic group comprising a benzene ring or an aromatic condensed ring, provided that one or more optional hydrogen atoms in the benzene ring or the aromatic condensed ring may be substituted by a monovalent organic group other than an amino group, and R is a C 1-10 bivalent saturated hydrocarbon group.

  本发明旨在提供一种液晶取向剂，能够形成具有良好电学特性、储存稳定性和生产率优异的液晶取向膜。液晶取向剂包括至少一种由二胺组分与四羧酸二酐组分聚合得到的聚酰胺酸和由聚酰胺酸环状脱水得到的聚酰亚胺，其特征在于二胺组分中包含下式[1]所表示的二胺之一：H2N-A-R—NH2[1]其中，A是一个双价的有机基团，包括苯环或芳香环，并且苯环或芳香环中的一个或多个可选氢原子可以被除氨基以外的一价有机基团取代，R是一个C1-10双价饱和碳氢基团。
• 6-Oxy-2,2,4-trialkyl-1,2-dihydroquinoline derivatives and diene rubber compositions containing them
  申请人：MONSANTO COMPANY

  公开号：EP0024816A1

  公开（公告）日：1981-03-11

  Vulcanizable or vulcanized diene elastomers containing stabilizing amounts of 6-oxy-2,2,4-trialkyl-1, 2-dihydroquinoline derivatives of the formula wherein the R1's are lower alkyl radicals, R is a straight or branched chain radical having the formula CnH2n+2-x where n is an integer from one to ten and x is an integer from two to four, show resistance to ozone attack. The 6-oxy-2,2,4- trialkyl-1, 2-dihydroquinoline derivatives themselves are novel compounds.

  可硫化或硫化二烯弹性体，含有稳定量的 6-氧基-2,2,4-三烷基-1,2-二氢喹啉衍生物，其式为 其中 R1 是低级烷基，R 是直链或支链基，其式为 CnH2n+2-x 其中 n 是 1 到 10 的整数，x 是 2 到 4 的整数。6-氧基-2,2,4-三烷基-1,2-二氢喹啉衍生物本身就是新型化合物。
• Thermotropic copolyazomethines and process for preparing them
  申请人：ENIRICERCHE S.p.A.

  公开号：EP0322943A2

  公开（公告）日：1989-07-05

  Thermotropic copolyazomethines having a mesophase temperature range lying within a desired range of values are obtained by copolymerizing terephthalic aldehyde with at least two different 1,n-bis(4-aminophenoxy)alkanes. Such copolya omethines are particularly useful as reinforcing materials for the usual thermoplastic poly­mers, such as polycarbonate, polybutyleneterephthalate, polyethyleneterephthalate and polyamides.

  通过对苯二甲醛与至少两种不同的 1,n-双（4-氨基苯氧基）烷烃共聚，可获得热致性共聚偶氮甲烷，其介相温度范围在所需值范围内。 这种共聚邻苯二甲酸酐特别适用于作为普通热塑性聚合物（如聚碳酸酯、聚对苯二甲酸丁二醇酯、聚对苯二甲酸乙二醇酯和聚酰胺）的增强材料。