trimethyl(5,6-benzoquinoline) aluminium(III) | 40961-80-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: trimethyl(5,6-benzoquinoline) aluminium(III)
• 英文别名: (benzo[f]quinoline-N)trimethylaluminium；aluminum;benzo[f]quinoline;carbanide
• CAS: 40961-80-6
• 化学式: C₁₆H₁₈AlN
• 分子量: 251.307
• InChiKey: CSFFTMMPEIKOPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.36
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5.6-苯并喹啉 、 三甲基铝 以 乙醚 为溶剂， 以95%的产率得到trimethyl(5,6-benzoquinoline) aluminium(III)
  参考文献：
  名称：

  Synthesis and characterization of adducts of R3M (R  Me, M  Al, Ga In) with 5,6-benzoquinoline: X-ray crystal structures of Me3GaBQ and ClMe2AlBQ (BQ = 5,6-benzoquinoline)

  摘要：

  The reaction of R(3)M and AlMe(2)Cl with 5,6-benzoquinoline (BQ) gave the Lewis acid-base adducts R(3)M-BQ [R = Me, M = Al (1), Ga (2), In (3)] and ClMe(2)Al-BQ (4). These adducts are much less air- and water-sensitive than the metal trialkyls and AlMe(2)Cl. All the compounds were characterized by elemental analyses, IR, NMR and mass spectroscopy. The X-ray crystal structures of 2 and 4 showed that gallium and aluminium atoms in the molecule were tetrahedrally coordinated.

  DOI：

  10.1016/0277-5387(95)00007-f

文献信息

• Adduct of AlMe3 with Benzo[f]quinoline
  作者：X. M. Wang、H. S. Sun、S. X. Wang、X. Y. Huang、X. Z. You

  DOI：10.1107/s0108270195009681

  日期：1996.1.15

  The reaction of AlMe(3) with benzo[f]quinoline gave the Lewis acid-base adduct Me(3)Al-BQ, (BQ = benzo[f]-quinoline) (benzo[f] quinoline-N)trimethylaluminium, [Al(CH3)(3)(C13H9N)]}, with an Al-N bond length of 2.057 (2) Angstrom. This adduct is much less air and water sensitive than the trialkyl metal. The complex was found to be a discrete 1:1 molecular adduct of trimethylaluminium bonded to BQ. The compound contains a tetracoordinate Al atom with distorted tetrahedral geometry.