3-N,6-N-bis[[amino(pyrimidin-2-yl)methylidene]amino]pyridazine-3,6-dicarboxamide | 959634-45-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 3-N,6-N-bis[[amino(pyrimidin-2-yl)methylidene]amino]pyridazine-3,6-dicarboxamide
• CAS: 959634-45-8
• 化学式: C₁₆H₁₄N₁₂O₂
• 分子量: 406.366
• InChiKey: AZDQPYBETDLYHY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  212
• 氢给体数：
  4
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  copper(II) bis(trifluoromethanesulfonate) 、 3-N,6-N-bis[[amino(pyrimidin-2-yl)methylidene]amino]pyridazine-3,6-dicarboxamide 在 KAg(CN)2 作用下， 以 甲醇 、 水 、 乙腈 为溶剂， 以38%的产率得到[Cu(II)12Cu(I)4(C4H2N2(CONNC(NH2)C4H3N2)2)8](CF3SO3)12*24water
  参考文献：
  名称：

  Magnetic [n × n] (n = 2−5) Grids by Directed Self-Assembly

  摘要：

  Polytopic hydrazone-based ligands are discussed in the context of the design attributes of the ligand and the power of self-assembly as a methodology for the synthesis of polymetallic systems with specific and predetermined organization of the metal centers in a closely spaced bridged arrangement. Magnetic exchange coupling occurs as a result of the close proximity of the metal ions. Homometallic, heterometallic, and mixed-spin-state [n x n] (n = 2-5) square grids are highlighted and discussed in terms of their structural and magnetic properties. Antiferromagnetic, ferromagnetic, and ferrimagnetic examples are described.

  DOI：

  10.1021/ic801078h
• 作为产物：
  描述：

  甲基2-嘧啶甲亚氨酸酯 、 Pyridazine-3,6-dicarboxylic acid bishydrazide 在 溶剂黄146 作用下， 以 甲醇 为溶剂， 反应 18.0h， 生成 3-N,6-N-bis[[amino(pyrimidin-2-yl)methylidene]amino]pyridazine-3,6-dicarboxamide
  参考文献：
  名称：

  自组装的磁耦合方形Cu16 4x [2x2]网格。

  摘要：

  DOI：

  10.1002/anie.200701840

文献信息

• Magnetic [<i>n</i> × <i>n</i>] (<i>n</i> = 2−5) Grids by Directed Self-Assembly
  作者：Louise N. Dawe、Konstantin V. Shuvaev、Laurence K. Thompson

  DOI：10.1021/ic801078h

  日期：2009.4.20

  Polytopic hydrazone-based ligands are discussed in the context of the design attributes of the ligand and the power of self-assembly as a methodology for the synthesis of polymetallic systems with specific and predetermined organization of the metal centers in a closely spaced bridged arrangement. Magnetic exchange coupling occurs as a result of the close proximity of the metal ions. Homometallic, heterometallic, and mixed-spin-state [n x n] (n = 2-5) square grids are highlighted and discussed in terms of their structural and magnetic properties. Antiferromagnetic, ferromagnetic, and ferrimagnetic examples are described.
• A Self-Assembled, Magnetically Coupled Square Cu16 4×[2×2] Grid
  作者：Louise N. Dawe、Laurence K. Thompson

  DOI：10.1002/anie.200701840

  日期：2007.10.1