1,3,5-tris(vinyloxy)adamantane | 500541-87-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,3,5-tris(vinyloxy)adamantane
• 英文别名: 1,3,5-tris(ethenoxy)adamantane
• CAS: 500541-87-7
• 化学式: C₁₆H₂₂O₃
• 分子量: 262.349
• InChiKey: VEPLBBDNMOCEMK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  、 disodium;carbonate 、 1,3,5-金刚烷三醇 、 乙酸乙烯酯 、 1,3,5-tris(vinyloxy)adamantane 、 3,5-bis(vinyloxy)-1-adamantanol 在 氩 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以5-vinyloxy-1,3-adamantanediol were produced的产率得到5-vinyloxy-1,3-adamantanediol
  参考文献：
  名称：

  Process for producing vinyl ether compounds

  摘要：

  该过程产生乙烯基醚化合物，包括使下式（1）所表示的乙烯酯化合物：1其中R1，R2，R3和R4相同或不同，且均为氢原子或有机基团，与下式（2）所表示的羟基化合物反应：R5OH  (2)其中R5为有机基团，在至少一种过渡金属化合物的存在下，从而产生下式（3）所表示的乙烯基醚化合物：2其中R2，R3，R4和R5的含义如上所定义。这样的过渡金属化合物包括铱化合物和其他含有第VIII族元素的化合物。

  公开号：

  US20030083529A1

文献信息

• Adamantyl vinyl ether compound and production process for the same
  申请人：Idemitsu Petrochemical Co., Ltd.

  公开号：EP1486480A1

  公开（公告）日：2004-12-15

  Provided by the present invention are an adamantyl vinyl ether compound which is useful as a monomer for functional resins in the photolithography field or a raw material therefor and medical and agricultural intermediates and a production process for the same. The present invention relates to a production process for an adamantyl vinyl ether compound, characterized by subjecting an adamantyl vinyl ether compound having a specific structure and alcohol having an eliminating group in a β position to chloroalkyl-etherification, then subjecting it to etherification to form an adamantyl group-containing ether and then subjecting it to vinyl-etherification.

  本发明提供了一种具有特定结构的脂肪基乙烯醚化合物，可用作光刻领域功能树脂的单体或其原料，以及医药和农业中间体，以及其生产工艺。本发明涉及一种脂肪基乙烯醚化合物的生产工艺，其特征在于将具有特定结构的脂肪基乙烯醚化合物和具有β位消除基团的醇经过氯烷醚化反应，然后经过醚化反应形成含有脂肪基的醚，最后经过乙烯醚化反应。
• PHOTOSENSITIVE COPOLYMER AND PHOTORESIST COMPOSITION
  申请人：Thackeray James W.

  公开号：US20120129105A1

  公开（公告）日：2012-05-24

  A copolymer has formula: wherein R 1 -R 5 are independently H, C 1-6 alkyl, or C 4-6 aryl, R 6 is a fluorinated or non-fluorinated C 5-30 acid decomposable group; each Ar is a monocyclic, polycyclic, or fused polycyclic C 6-20 aryl group; each R 7 and R 8 is —OR 11 or —C(CF 3 ) 2 OR 11 where each R 11 is H, a fluorinated or non-fluorinated C 5-30 acid decomposable group, or a combination; each R 9 is independently F, a C 1-10 alkyl, C 1-10 fluoroalkyl, C 1-10 alkoxy, or a C 1-10 fluoroalkoxy group; R 10 is a cation-bound C 10-40 photoacid generator-containing group, mole fractions a, b, and d are 0 to 0.80, c is 0.01 to 0.80, e is 0 to 0.50 provided where a, b, and d are 0, e is greater than 0, the sum a+b+c+d+e is 1, l and m are integers of 1 to 4, and n is an integer of 0 to 5. A photoresist and coated substrate, each include the copolymer.

  一种共聚物的化学式为：其中R1-R5独立地为H、C1-6烷基或C4-6芳基，R6为氟化或非氟化的C5-30酸分解基团；每个Ar为单环、多环或融合多环的C6-20芳基基团；每个R7和R8为—OR11或—C(CF3)2OR11，其中每个R11为H、氟化或非氟化的C5-30酸分解基团或其组合；每个R9独立地为F、C1-10烷基、C1-10氟烷基、C1-10烷氧基或C1-10氟烷氧基基团；R10为带正离子的C10-40光酸发生剂含基团，摩尔分数a、b和d为0至0.80，c为0.01至0.80，e为0至0.50，其中若a、b和d为0，则e大于0，a+b+c+d+e之和为1，l和m为1至4的整数，n为0至5的整数。一种光刻胶和涂层基板，均包括该共聚物。
• Vinyl ether compounds and preparation process thereof
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1288186A2

  公开（公告）日：2003-03-05

  A process produces vinyl ether compounds and includes allowing a vinyl ester compound represented by following Formula (1): wherein R1, R2, R3 and R4 are the same or different and are each a hydrogen atom or an organic group, to react with a hydroxy compound represented by following Formula (2):         R5OH     (2) wherein R5 is an organic group, in the presence of at least one transition element compound to thereby yield a vinyl ether compound represented by following Formula (3): wherein R2, R3, R4 and R5 have the same meanings as defined above. Such transition element compounds include iridium compounds and other compounds containing Group VIII elements. A vinyl ether compound represented by following Formula (4): wherein W is a divalent hydrocarbon; n is 0 or 1; m is an integer from 1 to 8; ring Z is any one of cyclic groups represented by following Formulae (5) through (12):

  一种生产乙烯基醚化合物的工艺，包括让下式（1）代表的乙烯基酯化合物与下式（2）代表的羟基化合物反应： 其中 R1、R2、R3 和 R4 相同或不同，且各自为氢原子或有机基团，与下式（2）所代表的羟基化合物反应： R5OH (2) 其中 R5 为有机基团，在至少一种过渡元素化合物存在的情况下，生成下式 (3) 所代表的乙烯基醚化合物： 其中 R2、R3、R4 和 R5 的含义与上述定义相同。此类过渡元素化合物包括铱化合物和其他含有第八族元素的化合物。 由下式（4）表示的乙烯基醚化合物： 其中 W 为二价烃；n 为 0 或 1；m 为 1 至 8 的整数；环 Z 为下式（5）至（12）所代表的任一环状基团：
• Vinyl ether compounds
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1826196A2

  公开（公告）日：2007-08-29

  A vinyl ether compound represent by following Formula (4): wherein ring Z is any one of cyclic groups represented by following Formulae (5) through (12): wherein X1, X2, X3, X4, X5, X6, X7, and X8 are each a substituent combined with an atom constituting each ring and are each a halogen atom, an alkyl group, a haloalkyl group, an aryl group, a hydroxyl group which may be protected by a protecting group, a hydroxymethyl group which may be protected by a protecting group, an amino group which may be protected by a protecting group, a carboxyl group which may be protected by a protecting group, a sulfo group which may be protected by a protecting group, an oxo group, a nitro group, a cyano group, or an acyl group which may be protected by a protecting group, wherein, when there are two or more substituents X1s, these X1s may be combined to form a ring containing four or more members with a carbon atom constituting the cyclohexane ring in Formula (5); a, b, c, d, e, f, g, and h are each an integer of 0 or more, wherein when a, b, c, d, 3, f, g or h is 2 or more, the substituents in the parentheses may be the same or different; and p, q, and r are each an integer of from 0 to 3; W is a divalent hydrocarbon group; R2, R3, and R4 are the same or different and are each a hydrogen atom or an organic group; n is 0 or 1; and m is an integer of from 1 to 8, wherein groups in the parentheses may be the same or different when m is 2 or more; wherein a in Formula (5) is 1 or more and b in Formula (6) is 1 or more when n is 0 and m is 1; and wherein c is 1 or more when p is 0 or 1, and X3 is a group other than hydroxyl group when p is 0 and c is 1 in Formula (7).

  乙烯基醚化合物，由下式（4）表示： 其中 环 Z 是下式（5）至（12）所代表的任何一个环状基团： 其中 X1、X2、X3、X4、X5、X6、X7 和 X8 各自是与构成各环的原子结合的取代基，并且各自是卤素原子、烷基、卤代烷基、芳基、可受保护基保护的羟基、可受保护基保护的羟甲基、可受保护基保护的氨基、可被保护基团保护的羧基、可被保护基团保护的磺基、氧代基团、硝基、氰基或可被保护基团保护的酰基，其中，当有两个或两个以上取代基 X1s 时，这些 X1s 可组合成一个包含四个或四个以上成员的环，其中一个碳原子构成式（5）中的环己烷环； a、b、c、d、e、f、g 和 h 各为 0 或 0 以上的整数，其中当 a、b、c、d、3、f、g 或 h 为 2 或 2 以上时，括号中的取代基可以相同或不同；以及 p、q 和 r 分别为 0 至 3 的整数； W 是二价烃基； R2、R3 和 R4 可以相同或不同，并且各自是氢原子或有机基团； n 是 0 或 1；以及 m 是 1 至 8 的整数、 当 m 为 2 或 2 以上时，括号中的基团可以相同或不同； 当 n 为 0 和 m 为 1 时，式（5）中的 a 为 1 或 1 以上，式（6）中的 b 为 1 或 1 以上；以及 其中当 p 为 0 或 1 时，式（7）中的 c 为 1 或 1 以上；当 p 为 0 和 c 为 1 时，式（7）中的 X3 为羟基以外的基团。
• ALKALI-DEVELOPABLE CURABLE COMPOSITION, INSULATING THIN FILM USING THE SAME, AND THIN FILM TRANSISTOR
  申请人：Kaneka Corporation

  公开号：EP2236543A1

  公开（公告）日：2010-10-06

  An object of the present invention is to provide a polysiloxane compound that can be developed in an aqueous alkali solution and can yield a cured product or thin film having superior heat-resistant transparency and insulating properties, a curable composition thereof, and a thin film transistor provided with a passivation layer or gate insulator using the same, and the present invention relates to a polysiloxane compound having at least one photopolymerizable functional group in a molecule thereof, and having at least one member selected from the group consisting of an isocyanuric acid backbone structure, a phenolic hydroxyl group and a carboxyl group within the same molecule, to a curable composition containing the polysiloxane compound, and to a cured product thereof.

  本发明的目的是提供一种可在碱水溶液中显影并可产生具有优异耐热透明性和绝缘性能的固化产品或薄膜的聚硅氧烷化合物、其固化组合物以及使用该化合物的带有钝化层或栅极绝缘体的薄膜晶体管、本发明涉及一种聚硅氧烷化合物，其分子中至少有一个可光聚合的官能团，并且在同一分子中至少有一个选自异氰尿酸骨架结构、酚羟基和羧基组成的组的成员；本发明还涉及一种含有该聚硅氧烷化合物的可固化组合物；本发明还涉及一种固化产品。