ADDTU | 1365536-22-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: ADDTU
• CAS: 1365536-22-6
• 化学式: C₄₄H₅₀N₄O₃S₃
• 分子量: 779.104
• InChiKey: UILQWPKJNBCGCS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.04
• 重原子数：
  54.0
• 可旋转键数：
  10.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  90.54
• 氢给体数：
  3.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  9-(4-nitrophenyl)-3,3,6,6,-tetramethyl-10-(2-thioctinoylaminophenyl)-3,4,6,7,9,10-hexahydro-1,8(2H,5H)-acridinedione 在 calcium chloride 、 锌 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 反应 24.0h， 生成 ADDTU
  参考文献：
  名称：

  Selective fluoride ion recognition by a thiourea based receptor linked acridinedione functionalized gold nanoparticles

  摘要：

  The design and synthesis of acridinedione functionalized gold nanoparticles based PET anion sensor 6 is described. The sensor 6 employs simple aromatic thiourea as anion receptors and the fluorophore is the acridinedione moiety, which were characterized by transmission electron microscopy (TEM), Fourier transform infrared (FT-IR), UV-vis, steady-state and time-resolved fluorescence techniques. Upon selective recognition of F in acetonitrile, the fluorescence emission of 6 was quenched with significant changes in the absorption spectrum. These changes are ascribed due to the hydrogen bonding and deprotonation of the thiourea receptor of ADDTU-GNPs. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2010.10.025