fac-Re(CO)3(2,2'-bipyridyl)(CH2OC(O)CH3) | 209532-59-2

• 英文名称: fac-Re(CO)3(2,2'-bipyridyl)(CH2OC(O)CH3)
• CAS: 209532-59-2
• 化学式: C₁₆H₁₃N₂O₅Re
• 分子量: 499.497
• InChiKey: IMBRIQLHVWXZDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 fac-Re(CO)3(2,2'-bipyridyl)(CH2OC(O)CH3) 以 甲醇 为溶剂， 以70%的产率得到[Re(CH2OCH3)(CO)3(2,2-bipyridine)]
  参考文献：
  名称：

  Synthesis and Reactions of fac-Re(bpy)(CO)₃(CH₂OR) (R = H, Acetyl; bpy = 2,2‘-Bipyridyl)

  摘要：

  Photoassisted reactions of fac-Re(bpy)(CO)(3)(CH2OR) (I, R = H; 2, R = OAc) and fac-Re(bpy)(CO)(3)CH2Ph (5) in MeOH provide fac-Re(bpy)(CO)(3)(OCH3) (3); 2 and 3 have been structurally characterized. Radical paths are indicated for 2 and 5; a nonradical path, involving photoassisted P-hydride elimination from the hydroxymethyl group, is proposed for 1.

  DOI：

  10.1021/om980102m
• 作为产物：
  描述：

  fac-Re(CO)3(2,2'-bipyridyl)(CH2OH) 、 溶剂黄146 以 溶剂黄146 为溶剂， 以86%的产率得到fac-Re(CO)3(2,2'-bipyridyl)(CH2OC(O)CH3)
  参考文献：
  名称：

  Synthesis and Reactions of fac-Re(bpy)(CO)₃(CH₂OR) (R = H, Acetyl; bpy = 2,2‘-Bipyridyl)

  摘要：

  Photoassisted reactions of fac-Re(bpy)(CO)(3)(CH2OR) (I, R = H; 2, R = OAc) and fac-Re(bpy)(CO)(3)CH2Ph (5) in MeOH provide fac-Re(bpy)(CO)(3)(OCH3) (3); 2 and 3 have been structurally characterized. Radical paths are indicated for 2 and 5; a nonradical path, involving photoassisted P-hydride elimination from the hydroxymethyl group, is proposed for 1.

  DOI：

  10.1021/om980102m