4-[(4-Octadecoxyphenyl)methylideneamino]phenol | 155813-42-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-[(4-Octadecoxyphenyl)methylideneamino]phenol
• CAS: 155813-42-6
• 化学式: C₃₁H₄₇NO₂
• 分子量: 465.72
• InChiKey: YJGVTALSXULQHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  34
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  41.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-[(4-Octadecoxyphenyl)methylideneamino]phenol 、 1,3-二溴丙烷 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 8.0h， 生成
  参考文献：
  名称：

  Synthesis and mesomorphic properties of 4-(4-bromopropyloxy)-4′-(4-alkyloxybenzylidene)anilines

  摘要：

  This article describes the preparation and liquid crystalline properties of a new homologous series of 4-(4-bromopropyloxy)-4'-(4-alkyloxybenzylidene)anilines in which the phenyl ring is armed by a bromopropyloxy chain. The thermal behavior and mesomorphic properties of the synthesized compounds were studied with particular attention given to the correlation between their phase transition temperatures and anisotropic change influenced by molecular structure. All the members displayed enantiotropic smectic phase except for the homologue with the longest alkyloxy chain (R = C18H37), exhibiting only monotropic characteristic. The presence of bromine atom from the propyloxy side chain is found to be capable of altering and influencing the mesomorphic properties. (C) 2012 Guan-Yeow Yeap. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2012.05.008
• 作为产物：
  描述：

  硬脂基溴 在 potassium carbonate 、 溶剂黄146 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 7.0h， 生成 4-[(4-Octadecoxyphenyl)methylideneamino]phenol
  参考文献：
  名称：

  Synthesis and mesomorphic properties of 4-(4-bromopropyloxy)-4′-(4-alkyloxybenzylidene)anilines

  摘要：

  This article describes the preparation and liquid crystalline properties of a new homologous series of 4-(4-bromopropyloxy)-4'-(4-alkyloxybenzylidene)anilines in which the phenyl ring is armed by a bromopropyloxy chain. The thermal behavior and mesomorphic properties of the synthesized compounds were studied with particular attention given to the correlation between their phase transition temperatures and anisotropic change influenced by molecular structure. All the members displayed enantiotropic smectic phase except for the homologue with the longest alkyloxy chain (R = C18H37), exhibiting only monotropic characteristic. The presence of bromine atom from the propyloxy side chain is found to be capable of altering and influencing the mesomorphic properties. (C) 2012 Guan-Yeow Yeap. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2012.05.008

文献信息

• Synthesis and mesomorphic properties of 4-(4-bromopropyloxy)-4′-(4-alkyloxybenzylidene)anilines
  作者：Guan-Yeow Yeap、Yew-Hong Ooi、Kenji Kubo、Masato M. Ito

  DOI：10.1016/j.cclet.2012.05.008

  日期：2012.7

  This article describes the preparation and liquid crystalline properties of a new homologous series of 4-(4-bromopropyloxy)-4'-(4-alkyloxybenzylidene)anilines in which the phenyl ring is armed by a bromopropyloxy chain. The thermal behavior and mesomorphic properties of the synthesized compounds were studied with particular attention given to the correlation between their phase transition temperatures and anisotropic change influenced by molecular structure. All the members displayed enantiotropic smectic phase except for the homologue with the longest alkyloxy chain (R = C18H37), exhibiting only monotropic characteristic. The presence of bromine atom from the propyloxy side chain is found to be capable of altering and influencing the mesomorphic properties. (C) 2012 Guan-Yeow Yeap. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.