trimesoyl chloride | 46427-54-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: trimesoyl chloride
• 英文别名: 5-Acetylbenzene-1,3-dicarbonyl chloride
• CAS: 46427-54-7
• 化学式: C₁₀H₆Cl₂O₃
• 分子量: 245.062
• InChiKey: JODUAVFKTWVNLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  trimesoyl chloride 、 (2,6-diisopropylphenyl)-4,4-diethyl-2,2-dimethylpyrrolidin-5-ylidene 以 正己烷 为溶剂， 反应 0.5h， 以58%的产率得到
  参考文献：
  名称：

  源自环状（烷基）（氨基）卡宾的可瓶装（氨基）（羧基）自由基

  摘要：

  单体（氨基）（羧基）自由基分两步合成：将稳定的环状（烷基）（氨基）卡宾添加到酰氯中，然后进行单电子还原。它们对二聚化的稳定性也允许合成相关的双自由基和三自由基。

  DOI：

  10.1021/ja4104765

文献信息

• PHOTOACTIVABLE NITROGEN BASES
  申请人：Dietliker Kurt

  公开号：US20100105794A1

  公开（公告）日：2010-04-29

  Compounds of the Formula (I), (II) and (III) wherein Ar is for example phenylene, biphenylene or naphthylene, all of which are unsubstituted or substituted by C 1 -C 4 -alkyl, C 2 -C 4 -alkenyl, CN, OR 11 , SR 11 , CH2OR 11 , COOR 12 , CONR 12 R 13 or halogen; R 1 , R 2 , R 7 and R 8 independently of one another other are hydrogen or C 1 -C 6 -alkyl; R 3 and R 5 together and R 4 and R 6 together form a C 2 -C 6 -alkylene bridge which is unsubstituted or substituted by one or more C 1 -C 4 -alkyl; R 11 is hydrogen or C 1 -C 6 -alkyl; R 12 and R 13 independently of one another for example are hydrogen, phenyl, C 1 -C 18 -alkyl, C 1 -C 18 -alkyl which is interrupted by one or more O; n is 1-10; X is O, S or NR 10 ; A and A 1 are suitable linking groups; are suitable as photolatent bases.

  公式(I)、(II)和(III)的化合物，其中Ar可以是苯基、联苯基或萘基，它们都可以是未取代或被C1-C4烷基、C2-C4烯基、CN、OR11、SR11、CH2OR11、COOR12、CONR12R13或卤素取代的；R1、R2、R7和R8独立地是氢或C1-C6烷基；R3和R5在一起，R4和R6在一起形成一个未取代或被一个或多个C1-C4烷基取代的C2-C6烷基桥；R11是氢或C1-C6烷基；R12和R13独立地可以是氢、苯基、C1-C18烷基、被一个或多个O中断的C1-C18烷基；n为1-10；X为O、S或NR10；A和A1是适当的连接基团；它们适用于光致潜基。
• Anion-binding polymers and uses thereof
  申请人：Ilypsa, Inc.

  公开号：EP2009042A1

  公开（公告）日：2008-12-31

  Anion-binding polymers are described. The anion-binding polymers in some cases are low swelling anion-binding polymers. In some cases, the anion-binding polymers have a pore volume distribution such that a fraction of the polymer is not available for non-interacting solutes above a certain percentage of the MW of the target ion for the polymer. In some cases, the anion-binding polymers are characterized by low ion-binding interference, where the interference is measured in, for example, a gastrointestinal simulant, relative to non-interfering buffer. Pharmaceutical composition, methods of use, and kits are also described.

  描述了阴离子结合聚合物。阴离子结合聚合物在某些情况下是低膨胀阴离子结合聚合物。在某些情况下，阴离子结合聚合物具有一定的孔体积分布，使聚合物中超过目标离子分子量一定百分比的部分不能用于非相互作用溶质。在某些情况下，阴离子结合聚合物具有离子结合干扰低的特点，其中干扰是在胃肠道模拟液等中相对于无干扰缓冲液测量的。还描述了药物组合物、使用方法和试剂盒。
• Method for monitoring cement using polymer-based capsules
  申请人：SAUDI ARABIAN OIL COMPANY

  公开号：US10947438B2

  公开（公告）日：2021-03-16

  Embodiments provide a method for monitoring structural integrity of a hardened cement. An aramide capsule, a cement, and a water to form a cement slurry. The cement slurry is set to form a hardened cement, where the aramide capsule is embedded in the hardened cement. Imperfections of the hardened cement are detected by measuring electrical resistivity of the hardened cement. The aramide capsule is formed by interfacial polymerization using a surfactant, a dispersed monomer, a crosslinker such that a semi-permeable membrane is formed surrounding a core.

  本实施例提供了一种监测硬化水泥结构完整性的方法。酰胺胶囊、水泥和水形成水泥浆。水泥浆凝固后形成硬化水泥，芳纶胶囊嵌入硬化水泥中。通过测量硬化水泥的电阻率来检测硬化水泥的缺陷。芳族聚酰胺胶囊是通过使用表面活性剂、分散单体和交联剂进行界面聚合形成的，从而在核心周围形成半透膜。
• US9921477B2
  申请人：——

  公开号：US9921477B2

  公开（公告）日：2018-03-20
• Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes
  作者：Janell K. Mahoney、David Martin、Curtis E. Moore、Arnold L. Rheingold、Guy Bertrand

  DOI：10.1021/ja4104765

  日期：2013.12.18

  Monomeric (amino)(carboxy) radicals were synthesized in two steps: the addition of a stable cyclic (alkyl)(amino) carbene to an acyl chloride, followed by a one-electron reduction. Their stability toward dimerization also allows for the synthesis of related bi- and triradicals.

  单体（氨基）（羧基）自由基分两步合成：将稳定的环状（烷基）（氨基）卡宾添加到酰氯中，然后进行单电子还原。它们对二聚化的稳定性也允许合成相关的双自由基和三自由基。