trans-1,4-cyclohexanediammonium galactarate | 1146598-27-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: trans-1,4-cyclohexanediammonium galactarate
• CAS: 1146598-27-7
• 化学式: C₆H₁₀O₈*C₆H₁₄N₂
• 分子量: 324.331
• InChiKey: NBJZKYANCABNHV-CKHAQEHSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.19
• 重原子数：
  22.0
• 可旋转键数：
  5.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  207.56
• 氢给体数：
  8.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  甲醇 、 trans-1,4-cyclohexanediammonium galactarate 在 乙酰氯 作用下， 反应 4.0h， 生成 dimethyl galactarate 、 trans-1,4-diaminocyclohexane dihydrochloride
  参考文献：
  名称：

  Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates

  摘要：

  Polyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.

  DOI：

  10.1080/07328300903080749
• 作为产物：
  描述：

  meso-galactaric acid 、 trans-1,4-Diaminocyclohexane 以 水 为溶剂， 反应 16.0h， 以92.7%的产率得到trans-1,4-cyclohexanediammonium galactarate
  参考文献：
  名称：

  Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates

  摘要：

  Polyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.

  DOI：

  10.1080/07328300903080749