[Ni(dimethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]tetraazacyclotetradecine-13,18-dicarboxylate)] | 69198-62-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Ni(dimethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]tetraazacyclotetradecine-13,18-dicarboxylate)]
• CAS: 69198-62-5
• 化学式: C₂₂H₁₈N₄NiO₆
• 分子量: 493.098
• InChiKey: JVYKBJBEWYMUFF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  manganese(II) perchlorate hexahydrate 、 [Ni(dimethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]tetraazacyclotetradecine-13,18-dicarboxylate)] 、 potassium thioacyanate 以 甲醇 、 水 为溶剂， 以10%的产率得到[Mn(Ni(dianion of Me2-5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]tetraazacyclotetradecine-13,18-dicarboxylate))2(NCS)2]n
  参考文献：
  名称：

  Appreciable Ni⋯O interactions at distances almost equal to the sum of the van der Waals radii of the two atoms

  摘要：

  Two new entities [Co(NiL)(2)(SCN)(2)](n) (1) and [Mn(NiL)(2)(NCS)(2)](n) (2) were prepared by using a macrocyclic oxamido mononuclear complex ligand NiL, and characterized by X-ray single crystal analyses. L denotes the dianion of dimethyl 5,6,7,8,15,16-hexahydro6,7-dioxodibenzo[1,4,8,11]tetraazacyclotetradecine-13,18-dicarboxylate. Ni...O contacts (3.092 angstrom) almost equal to the sum of the van der Waals radii of the two atoms were observed both in 1 and 2, and IR spectra support that appreciable coordination occurs at such long contacts. I and 2 are ID coordination polymers incorporating bimetallamacrocycles with the very long Ni...O coordination bonds as a kind of linking interaction. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.07.012
• 作为产物：
  描述：

  nickel(II) acetate tetrahydrate 、 dimethyl 2,2'-oxalyldiiminobis(phenylglyoxylate) 、 乙二胺 在 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以70%的产率得到[Ni(dimethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]tetraazacyclotetradecine-13,18-dicarboxylate)]
  参考文献：
  名称：

  Black, David St. C.; Moss, G. Ian, Australian Journal of Chemistry, 1987, vol. 40, # 1, p. 129 - 142

  摘要：

  DOI：