Acetic acid (2R,3R,4R,5R)-4,5-diacetoxy-2-((R)-1-tert-butoxycarbonylamino-2-hydroxy-ethyl)-tetrahydro-furan-3-yl ester | 127257-36-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Acetic acid (2R,3R,4R,5R)-4,5-diacetoxy-2-((R)-1-tert-butoxycarbonylamino-2-hydroxy-ethyl)-tetrahydro-furan-3-yl ester
• CAS: 127257-36-7
• 化学式: C₁₇H₂₇NO₁₀
• 分子量: 405.402
• InChiKey: ICYUIYRSMPVQHA-RYPNDVFKSA-N

反应信息

• 作为产物：
  描述：

  1,1-Dimethylethyl<2R-<2α(R^*),3β,4β,5α>>-2,2-dimethyl-4-(3,4,5-tris(acetyloxy)tetrahydro-2-furanyl)-3-oxazolidinecarboxylate 在 溶剂黄146 作用下， 反应 4.0h， 生成 Acetic acid (2R,3R,4R,5R)-4,5-diacetoxy-2-((R)-1-tert-butoxycarbonylamino-2-hydroxy-ethyl)-tetrahydro-furan-3-yl ester 、 Acetic acid (2R,3R,4R,5S)-4,5-diacetoxy-2-((R)-1-tert-butoxycarbonylamino-2-hydroxy-ethyl)-tetrahydro-furan-3-yl ester
  参考文献：
  名称：

  Glycosyl .alpha.-amino acids via stereocontrolled buildup of a penaldic acid equivalent. A novel synthetic approach to the nucleosidic component of the polyoxins and related substances

  摘要：

  DOI：

  10.1021/jo00299a017