| 241821-82-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 241821-82-9
• 化学式: C₃₄H₆₈O₄P₂Pd
• 分子量: 709.279
• InChiKey: PREBDXQKQJQBKX-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  bis(acetylacetonato)palladium(II) 、 三丁基膦 以 苯 为溶剂， 生成 [(acetylacetonate)Pd(C(3)-acetylacetonate)PBu3] 、 、
  参考文献：
  名称：

  摘要：

  Mechanisms of reactions between palladium bis(acetylacetonate) and tertiary and secondary phosphines and alkali-metal diphenyl phosphides are discussed. Depending on the conditions, either complex formation or redox processes occur. The mechanism of formation and the nature of microheterogeneous catalysts for hydrogenation are considered using palladium acetylacetonate complexes with tertiary phosphines as an example. Data of NMR and IR spectroscopies, electron microscopy, and X-ray powder diffraction analysis showed that the catalysts are a palladium organophosphorus matrix with nanosize and with immobilized palladium clusters in the zero oxidation state.

  DOI：

  10.1023/a:1014223932310