bis(5-amino-2,2,6,6-tetramethyl-4-hepten-3-onato)copper | 113475-94-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis(5-amino-2,2,6,6-tetramethyl-4-hepten-3-onato)copper
• CAS: 113475-94-8
• 化学式: C₂₂H₄₀CuN₂O₂
• 分子量: 428.118
• InChiKey: OKAYXNNWNOUQPI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 5-Amino-2,2,6,6-tetramethyl-4-hepten-3-on 在 NH₃ 作用下， 以 乙醇 、 氨 为溶剂， 以70%的产率得到bis(5-amino-2,2,6,6-tetramethyl-4-hepten-3-onato)copper
  参考文献：
  名称：

  Synthesis and properties of a new ketoiminate derivative of the 2,2,6,6-tetramethylheptane-3,5-dionate ligand to prepare volatile CVD precursors

  摘要：

  The beta-ketoimine (CH3)(3)CC(NH2)CHC(O)C(CH3)(3) (1) was synthesized by amination with dry ammonia in the presence of TiCl4. M.p. = 131 degrees C. IR and H-1 and C-13 NMR spectroscopic characterization indicates that the structure of a solution of 1 is the ketone form, and a single-crystal X-ray diffraction study shows that the structure of I is the enaminoketone form. The reaction of I with copper(II) and nickel(II) salts in solution gave chelate metal complexes: Cu[(CH3)(3)CC(NH)CHC(O)C(CH3)(3)](2) (2), M.p. = 209 degrees C, and Ni[(CH3)(3)CC(NH)CHC(O)C(CH3)(3)](2) (3), M.p. = 267 degrees C. These complexes are volatile and sublime at 180-190 degrees C at 5 x 10(-3) Torr. An X-ray diffraction study reveals that these metal complexes are monomeric and isostructural in the solid state. In compound 2, the Cu atom has a square coordination environment: Cu-OZ approximate to Cu-N = 1.91 angstrom, angle O-Cu-N = 91.81 angstrom. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.05.046

文献信息

• Dietrich, Klaus; Koenig, Klaus; Mattern, Guenter, Chemische Berichte, 1988, vol. 121, p. 1277 - 1284
  作者：Dietrich, Klaus、Koenig, Klaus、Mattern, Guenter、Musso, Hans

  DOI：——

  日期：——