(4-Aminophenyl)-(2,4,6-trihydroxyphenyl)methanone | 499973-17-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-Aminophenyl)-(2,4,6-trihydroxyphenyl)methanone
• CAS: 499973-17-0
• 化学式: C₁₃H₁₁NO₄
• 分子量: 245.235
• InChiKey: JHVHQFZTOYAYSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  104
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-[5-(溴甲基)吡啶-2-基]-5-甲基吡啶 、 (4-Aminophenyl)-(2,4,6-trihydroxyphenyl)methanone 在 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 48.0h， 以42%的产率得到(4-Amino-phenyl)-[2,4,6-tris-(5'-methyl-[2,2']bipyridinyl-5-ylmethoxy)-phenyl]-methanone
  参考文献：
  名称：

  Phloroglucinol based podands, versatile tripodal ligands

  摘要：

  The synthesis of four phloroglucinol based podands is described. Ligands 4 and 5 have three bipyridine arms and an induced octahedral cavity ideal for transition metal complexation. The iron(II) complex of 4 is described. Tripodes 6 and 7 possess three bipyridine-carboxylate arms, and are designed for the encapsulation of luminescent lanthanide salts. Some preliminary optical properties of the corresponding Eu3+ and Tb3+ are presented. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)02213-x
• 作为产物：
  描述：

  间苯三酚 在 palladium on activated charcoal 二硫化碳 、 三氯化铝 、 氢气 作用下， 以 乙醇 、 硝基苯 为溶剂， 生成 (4-Aminophenyl)-(2,4,6-trihydroxyphenyl)methanone
  参考文献：
  名称：

  Phloroglucinol based podands, versatile tripodal ligands

  摘要：

  The synthesis of four phloroglucinol based podands is described. Ligands 4 and 5 have three bipyridine arms and an induced octahedral cavity ideal for transition metal complexation. The iron(II) complex of 4 is described. Tripodes 6 and 7 possess three bipyridine-carboxylate arms, and are designed for the encapsulation of luminescent lanthanide salts. Some preliminary optical properties of the corresponding Eu3+ and Tb3+ are presented. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)02213-x

文献信息

• Phloroglucinol based podands, versatile tripodal ligands
  作者：Gilles Ulrich、Sébastien Bedel、Claude Picard

  DOI：10.1016/s0040-4039(02)02213-x

  日期：2002.12

  The synthesis of four phloroglucinol based podands is described. Ligands 4 and 5 have three bipyridine arms and an induced octahedral cavity ideal for transition metal complexation. The iron(II) complex of 4 is described. Tripodes 6 and 7 possess three bipyridine-carboxylate arms, and are designed for the encapsulation of luminescent lanthanide salts. Some preliminary optical properties of the corresponding Eu3+ and Tb3+ are presented. (C) 2002 Elsevier Science Ltd. All rights reserved.