4-仲-丁基-环己醇 | 6292-20-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 4-仲-丁基-环己醇
• 英文名称: p-s-Butylcyclohexanol
• 英文别名: (+/-)-1-sek.-Butyl-cyclohexanol-(4)；(+/-)-4-Hydroxy-1-sek.-butyl-cyclohexan；4-sec-Butyl-cyclohexanol；2-(4-Oxy-cyclohexyl)-butan；4-cis-(1-methylpropyl)cyclohexanol；4-s-butyl-cyclohexanol；Cyclohexanol, 4-sec-butyl-；4-butan-2-ylcyclohexan-1-ol
• CAS: 6292-20-2
• 化学式: C₁₀H₂₀O
• 分子量: 156.268
• InChiKey: NSMFWUVWJSHYTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-仲-丁基-环己醇 在 氢氧化钾 作用下， 生成 2-[2-(4-sec-butyl-cyclohexyl)-ethyl]-3-methyl-valeric acid
  参考文献：
  名称：

  Alpha-alkyl, 4-alkyl cyclohexylbutyric acids

  摘要：

  公开号：

  US02560242A1
• 作为产物：
  描述：

  双酚B 在 氢气 作用下， 生成 4-仲-丁基-环己醇
  参考文献：
  名称：

  DE478273

  摘要：

  公开号：

文献信息

• [EN] BICYCLIC ARYL SPHINGOSINE 1-PHOSPHATE ANALOGS<br/>[FR] ANALOGUES DE SPHINGOSINE 1-PHOSPHATE D'ARYLE BICYCLIQUE
  申请人：BIOGEN IDEC INC

  公开号：WO2010051030A1

  公开（公告）日：2010-05-06

  Compounds that have agonist activity at one or more of the SlP receptors are provided. The compounds are sphingosine analogs that, after phosphorylation, can behave as agonists at S lP receptors.

  提供了一种或多种SlP受体的激动剂活性的化合物。这些化合物是鞘氨醇类似物，磷酸化后可以在SlP受体上表现为激动剂。
• METHOD FOR PRODUCING CARBOXYLIC ACID ESTERS AND THE USE THEREOF AS PLASTICIZERS
  申请人：BASF SE

  公开号：US20160264509A1

  公开（公告）日：2016-09-15

  The present invention relates to a process for the production of carboxylic esters by reaction of carboxylic acids and/or carboxylic anhydrides with at least one alcohol selected from alkanols having at least 5 carbon atoms, cycloalkanols, and alkoxy-alkanols, in the presence of an acidic esterification catalyst. The invention further relates to the use of the resultant carboxylic esters as plasticizers or in a plasticizer composition for thermoplastic polymers and elastomers.

  本发明涉及一种通过将羧酸和/或酸酐与至少一种来自至少有5个碳原子的脂肪醇、环脂醇和烷氧基脂肪醇中选择的醇在酸性酯化催化剂存在下反应制备羧酸酯的方法。该发明还涉及将所得的羧酸酯用作塑化剂或在热塑性聚合物和弹性体的塑化剂组合物中的用途。
• The preparation of cis- and trans-1-alkyl-4-phthalimidocyclohexanes
  作者：H. Booth、G. C. Gidley、P. R. Thornburrow

  DOI：10.1039/j29710001047

  日期：——

  Mixtures of cis- and trans-4-alkylcyclohexylamines (alkyl = methyl, ethyl, isopropyl, s-butyl, cyclohexyl, and t-butyl) have been prepared by standard methods and have been converted into stereochemically pure cis- and trans-1-alkyl-4-phthalimidocyclohexanes.

  顺式和反式-4-烷基环己胺（烷基=甲基，乙基，异丙基，仲丁基，环己基和叔丁基）的混合物已通过标准方法制备，并已转化为立体化学纯的顺式和反式-1-烷基-4-邻苯二甲酰亚胺基环己烷。
• Stereoselective Aromatic Ring Hydrogenation over Supported Rhodium Catalysts in Supercritical Carbon Dioxide Solvent
  作者：M. Shirai、N. Hiyoshi、C. V. Rode

  DOI：10.1002/tcr.201800128

  日期：2019.9

  The combination of supported rhodium metal catalysts and supercritical carbon dioxide solvent was effective for the stereoselective ring hydrogenations of aromatic compounds at low temperature. Higher solubility of hydrogen in supercritical carbon dioxide provides higher concentration of hydrogen on the rhodium surface, but lower that of the intermediate on rhodium surface, which suppresses the flipping

  负载型铑金属催化剂和超临界二氧化碳溶剂的组合对于芳族化合物在低温下的立体选择环氢化有效。氢在超临界二氧化碳中的较高溶解度使铑表面上的氢浓度更高，但铑表面上的中间体的浓度更低，这抑制了表面中间体的翻转，从而导致了更高的催化剂活性和对相应环加氢的顺式选择性产品与有机溶剂相比。
• TETRAHYDROFURAN DERIVATIVES AND USE THEREOF AS PLASTICIZERS
  申请人：BASF SE

  公开号：US20160075671A1

  公开（公告）日：2016-03-17

  The invention relates to tetrahydrofuran derivatives of general formula (I), wherein X stands for *—(C═O)—O—, *—(CH2)n-O—, or *—(CH2)n-O—(C═O)—, wherein * represents the point of bonding to the tetrahydrofuran ring and n has the value 0, 1, or 2; and R1 and R2 are selected independently of each other from among C4-C5 alkyl and C5-C6 cycloalkyl, wherein the cycloalkyl groups are unsubstituted or can be substituted by at least one C1-C10 alkyl group, a plasticizer composition that contains said tetrahydrofuran derivatives, molding masses that contain a thermoplastic polymer or an elastomer and such a tetrahydrofuran derivative. The invention further relates to a method for producing said tetrahydrofuran derivatives, and to the use of said tetrahydrofuran derivatives

  该发明涉及一般式(I)的四氢呋喃衍生物，其中X代表*—(C═O)—O—、*—(CH2)n-O—或*—(CH2)n-O—(C═O)—，其中*代表与四氢呋喃环的连接点，n的值为0、1或2；R1和R2分别从C4-C5烷基和C5-C6环烷基中独立选择，其中环烷基可以是未取代的或可以被至少一个C1-C10烷基基团取代，含有所述四氢呋喃衍生物的增塑剂组合物，含有热塑性聚合物或弹性体以及该四氢呋喃衍生物的成型物料。该发明还涉及制备所述四氢呋喃衍生物的方法，以及使用所述四氢呋喃衍生物。

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