[(acetylacetonate)Pd(C(3)-acetylacetonate)PBu3] | 168477-61-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(acetylacetonate)Pd(C(3)-acetylacetonate)PBu3]
• CAS: 168477-61-0
• 化学式: C₂₂H₄₁O₄PPd
• 分子量: 506.959
• InChiKey: MUXFLUUZESVMBV-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  bis(acetylacetonato)palladium(II) 、 三丁基膦 以 苯 为溶剂， 以65%的产率得到[(acetylacetonate)Pd(C(3)-acetylacetonate)PBu3]
  参考文献：
  名称：

  Belykh, L. B.; Dmitrieva, T. V.; Zinchenko, S. V., Russian Journal of Coordination Chemistry, 1995, vol. 21, p. 455 - 460

  摘要：

  DOI：

文献信息

• ——
  作者：F. K. Shmidt、L. B. Belykh、T. V. Goremyka

  DOI：10.1023/a:1014223932310

  日期：——

  Mechanisms of reactions between palladium bis(acetylacetonate) and tertiary and secondary phosphines and alkali-metal diphenyl phosphides are discussed. Depending on the conditions, either complex formation or redox processes occur. The mechanism of formation and the nature of microheterogeneous catalysts for hydrogenation are considered using palladium acetylacetonate complexes with tertiary phosphines as an example. Data of NMR and IR spectroscopies, electron microscopy, and X-ray powder diffraction analysis showed that the catalysts are a palladium organophosphorus matrix with nanosize and with immobilized palladium clusters in the zero oxidation state.
• Belykh; Dmitrieva; Shmidt, Russian Journal of Coordination Chemistry, <hi>1999</hi>, vol. 25, # 7, p. 494 - 498
  作者：Belykh、Dmitrieva、Shmidt

  DOI：——

  日期：——