[7,8,12,13,17,18-hexa-(4-tert-butylphenyl)-2,3-di-(quinoline-2-carboxamido)porphyrazinato]zinc(II) | 888015-08-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [7,8,12,13,17,18-hexa-(4-tert-butylphenyl)-2,3-di-(quinoline-2-carboxamido)porphyrazinato]zinc(II)
• CAS: 888015-08-5
• 化学式: C₉₆H₉₂N₁₂O₂Zn
• 分子量: 1511.26
• InChiKey: JRNVPSJNVXBUFI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [7,8,12,13,17,18-hexa-(4-tert-butylphenyl)-2,3-di-(quinoline-2-carboxamido)porphyrazinato]zinc(II) 、 copper dichloride 在 (CH₃)2NCHO 、 1,8-diazabicyclo[5.4.0]undec-7-ene 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以25%的产率得到N',N',N'',N''-dicopper(II) di-([7,8,12,13,17,18-hexa-(4-tert-butylphenyl)-2,3-di-(quinoline-2-carboxamido)porphyrazinato])zinc(II)
  参考文献：
  名称：

  Porphyrazines as Molecular Scaffolds:  Flexible Syntheses of Novel Multimetallic Complexes

  摘要：

  Reductive deselenation of selenodiazole-fused porphyrazines, followed by acylation of the resultant labile porphyrazinediamines, was used to prepare macrocycles bearing two Collins ligands, two oxamido residues, or two quinoline-2-carboxamido units. Peripheral coordination of copper(II) to the di-(quinoline-2-carboxamido)porphyrazine gave a metal-linked face-to-face porphyrazine dimer array. Sequential derivatization of the two amino groups in the porphyrazinediamines was used to prepare mixed peripheral ligand systems including a dimetallic picolinamido-Schiff base porphyrazine. Such systems exhibit strong metal-metal spin coupling and are anticipated to be of value in the synthesis of novel electronic and magnetic materials.

  DOI：

  10.1021/ic060176n
• 作为产物：
  描述：

  喹醛酰氯 、 在 C₅H₅N 作用下， 以 吡啶 为溶剂， 生成 [7,8,12,13,17,18-hexa-(4-tert-butylphenyl)-2,3-di-(quinoline-2-carboxamido)porphyrazinato]zinc(II)
  参考文献：
  名称：

  Porphyrazines as Molecular Scaffolds:  Flexible Syntheses of Novel Multimetallic Complexes

  摘要：

  Reductive deselenation of selenodiazole-fused porphyrazines, followed by acylation of the resultant labile porphyrazinediamines, was used to prepare macrocycles bearing two Collins ligands, two oxamido residues, or two quinoline-2-carboxamido units. Peripheral coordination of copper(II) to the di-(quinoline-2-carboxamido)porphyrazine gave a metal-linked face-to-face porphyrazine dimer array. Sequential derivatization of the two amino groups in the porphyrazinediamines was used to prepare mixed peripheral ligand systems including a dimetallic picolinamido-Schiff base porphyrazine. Such systems exhibit strong metal-metal spin coupling and are anticipated to be of value in the synthesis of novel electronic and magnetic materials.

  DOI：

  10.1021/ic060176n