[(MeCOCH2CMe2Ge)4(μ-S)6] | 102911-49-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(MeCOCH2CMe2Ge)4(μ-S)6]
• 英文别名: 4-methyl-4-[3,5,7-tris(2-methyl-4-oxopentan-2-yl)-2,4,6,8,9,10-hexathia-1,3,5,7-tetragermatricyclo[3.3.1.13,7]decan-1-yl]pentan-2-one
• CAS: 102911-49-9
• 化学式: C₂₄H₄₄Ge₄O₄S₆
• 分子量: 879.367
• InChiKey: VZRZOUVKUDEIEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(MeCOCH2CMe2Ge)4(μ-S)6] 、 一水合肼 以 二氯甲烷 为溶剂， 以72.4%的产率得到(NH3NH2)2[(H2NNCMeCH2CMe2Ge)2(μ-S)2S2]
  参考文献：
  名称：

  Facile Access to the Hydrazone Functionalized PdGeS Cluster [{R^NGe(μ-S)₃}₄Pd₆] from the Thiogermanate Anion [{R^NGe}₂(μ-S)₂S₂]²⁻

  摘要：

  The decanuclear ternary PdGeS cluster [{(RGe)-Ge-N(mu-S)(3)}(4)Pd-6] center dot MeOH (2 center dot MeOH) has been obtained in high yield by a two-step reaction, involving the derivatization of the carbonyl functionalized adamantane-like [((RGe)-Ge-1)(4)(mu-S)(6)] (R-1 = CMe2CH2COMe) with N2H4 center dot H2O, and a subsequent reaction of the resulting hydrazone functionalized thiogermanate (NH3NH2)(2)[((RGe)-Ge-N)(2)(mu-S)(2)S-2] (R-N=CMe2CH2CMeNNH2, 1) with an acidic solution of (N,N'-tmeda)Pd(NO3)(2), Cluster 2 has an elegant molecular structure which can be viewed as an R-N ligated ensemble of four edge-sharing [Pd3GeS3] defect hetercubanes that meet at an unoccupied center. Thus, the cluster consists of six square-planar coordinated Pd-II ions at the vertices of a regular octahedron with four faces capped by four [(RGeS3)-Ge-N](3-) units. The title compounds were structurally characterized by means of single-crystal X-ray diffraction as well as physical property measurements. Moreover, density functional theory calculations were performed to gain insight into the unique coordination situation of the hydrazone substituent.

  DOI：

  10.1021/ic900853e
• 作为产物：
  描述：

  4-methyl-4-(trichlorogermyl)-2-pentanone 、 硫化氢 、 吡啶 以63%的产率得到
  参考文献：
  名称：

  KAKIMOTO, NORIHIRO;MATSUI, MASANAO;TAKADA, TOYOZO;AKIBA, MITSUO, HETEROCYCLES, 1985, 23, N 10, 2681-2684

  摘要：

  DOI：