[N,N'-1,3-(2-nitropropanediyl)bis(oxazolidine-4-carboxylato)]copper(II) | 949148-13-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [N,N'-1,3-(2-nitropropanediyl)bis(oxazolidine-4-carboxylato)]copper(II)
• CAS: 949148-13-4
• 化学式: C₁₁H₁₅CuN₃O₈
• 分子量: 380.801
• InChiKey: MHFHHZXUEOZWCR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  聚合甲醛 、 硝基甲烷 、 水 、 copper(II) glycinate monohydrate 在 sodium carbonate 作用下， 以 乙醇 、 水 为溶剂， 以56%的产率得到[N,N'-1,3-(2-nitropropanediyl)bis(oxazolidine-4-carboxylato)]copper(II)
  参考文献：
  名称：

  Syntheses, characterization and catalytic activity of Mannich aminomethylation products of bis(glycinato)metal(II) complexes

  摘要：

  Mannich aminomethylation products have been prepared from one-pot template condensation of bis(glycinato)metal(II) complexes, M(gly)(2), with formaldehyde and nitromethane. The synthesized compounds were characterized by suitable spectroscopic and analytical methods such as UV-Vis, infrared spectroscopy, elemental analysis, FAB mass, ESR, cyclic voltammetry, TGA and NMR. One of the synthesized products has been used as catalyst in the hydrogen peroxide induced degradation of pyrocatechol violet (PCV) dye. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.03.018