cadmium(II) gematoporphyrin | 79857-41-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cadmium(II) gematoporphyrin
• CAS: 79857-41-3
• 化学式: C₃₈H₄₄CdN₄O₆
• 分子量: 765.201
• InChiKey: XTNQFYRQERRUJO-XVSNTGNMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cadmium(II) gematoporphyrin 、 cobalt(II) chloride 以 乙腈 为溶剂， 生成 cobalt(II) tetramethylhematoporphyrin
  参考文献：
  名称：

  Kinetics of the metal-exchange reaction of deuteroporphyrin and gematoporphyrin cadmium complexes with cobalt chloride in acetonitrile

  摘要：

  The metal-exchange reaction of cadmium deuteroporphyrin (CdDP) and cadmium gematoporphyrin (CdGP) with cobalt chloride in acetonitrile is studied spectrophotometrically. The stoichiometry of the metal-exchange reaction is determined. The results are compared with the exchange reaction of cadmium mesoporphyrin and cadmium protoporphyrin with cobalt acetate in acetonitrile. Substituents in the 2,4-positions of cadmium complexes of protoporphyrins are shown to influence the rate of the metal-exchange reaction. The increasing order of the rates of the metal-exchange reaction between protoporphyrins and cobalt chloride in acetonitrile is established.

  DOI：

  10.1134/s0036023607080177
• 作为产物：
  描述：

  tetramethyl hematoporphyrine 、 cadmium(II) chloride 以 吡啶 、 甲醇 、 氨 为溶剂， 生成 cadmium(II) gematoporphyrin
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cd: SVol., 19.1, page 771 - 774

  摘要：

  DOI：

文献信息

• Cadmium(II) for zinc(II) exchange reactions in deutero- and hematoporphyrin complexes in dimethyl sulfoxide
  作者：S. V. Zvezdina、E. V. Kozgova、M. B. Berezin、B. D. Berezin

  DOI：10.1134/s0036023607090197

  日期：2007.9

  The metal-exchange reaction between Cd-deuteroporphyrin or Cd-ematoporphyrin and ZnCl2 in dimethyl sulfoxide (DMSO) was studied spectrophotometrically. The order and activation parameters of the reaction of Cd2+ replacement by zinc ions were calculated. A mechanism of this reaction is suggested. The results are compared with the available data on metal-exchange reactions between Cd-mesoporphyrin and Cdprotoporphyrin and ZnCl2 in DMSO.
• Haurowitz, F.; Clar, E.; Hermann, Z., Chemische Berichte, 1935, vol. 68, p. 1795 - 1806
  作者：Haurowitz, F.、Clar, E.、Hermann, Z.、Kittel, H.、Muenzberg, F. K.

  DOI：——

  日期：——