N,N’-bis(isobutyl)perylene-3,4,9,10-bis(dicarboximide) | 72667-57-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N’-bis(isobutyl)perylene-3,4,9,10-bis(dicarboximide)
• 英文别名: 7,18-Bis(2-methylpropyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 72667-57-3
• 化学式: C₃₂H₂₆N₂O₄
• 分子量: 502.569
• InChiKey: YKHBUKPXKBPRTJ-UHFFFAOYSA-N

物化性质

• 沸点：
  711.6±33.0 °C(Predicted)
• 密度：
  1.379±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  38
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3,4,9,10-苝四羧酸二酐 、 异丁胺 以10%的产率得到
  参考文献：
  名称：

  NAGAO YUKINORI; MISONO TAKAHISA, BULL. CHEM. SOC. JAP., 1981, 54, NO 4, 1191-1194

  摘要：

  DOI：

文献信息

• Synthesis and Reactions of Perylenecarboxylic Acid Derivatives. VIII. Synthesis of<i>N</i>-Alkyl-3,4:9,10-Perylenetetracarboxylic Monoanhydride Monoimide
  作者：Yukinori Nagao、Takahisa Misono

  DOI：10.1246/bcsj.54.1191

  日期：1981.4

  The condensations of 3,4 : 9,10-perylenetetracarboxylic dianhydride with alkylamines (isobutyl-, pentyl-, hexyl-, and octylamines) were spectroscopically determined. Under all of the reaction conditions employed, N-alkyl-3,4 : 9,10-perylenetetracarboxylic monoanhydride monoimide (2a–d) (alkyl=a; isobutyl, b; pentyl, c; hexyl, d; octyl) were obtained. As the reaction proceeded, the yield of 2a–d increased at an initial stage but decreased gradually after reaching a maximum. This maximum yield of 2a–d was: 2a; 85–88%, 2b; 85–89%, 2c; 78–84%, 2d; 79–85%. The kinetics of the reaction were also examined.

  通过光谱测定3,4 : 9,10-苝四甲酸二酐与烷基胺（异丁基、戊基、己基和辛基胺）的缩合物。在所有反应条件下，均获得了N-烷基-3,4 : 9,10-苝四甲酸单酐单酰亚胺（2a–d）（烷基=a；异丁基、b；戊基、c；己基、d；辛基）。随着反应的进行，2a–d的产量在初始阶段增加，但在达到最大值后逐渐下降。2a–d的最大产量为：2a；85–88%，2b；85–89%，2c；78–84%，2d；79–
• RED FLUORESCENCE CONVERSION MEDIUM, COLOR CONVERSION SUBSTRATE USING SAME, AND LIGHT-EMITTING DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1868419A1

  公开（公告）日：2007-12-19

  A red fluorescence conversion medium including; a light-transmitting medium, a first perylene fluorescent dye that emits red fluorescence, and a second fluorescent dye that absorbs light in a ultraviolet to blue region to emit fluorescence, wherein the first perylene fluorescent dye absorbs light containing the fluorescence emitted by the second fluorescent dye to emit fluorescence.

  一种红色荧光转换介质，包括：透光介质、可发出红色荧光的第一亚珀尔荧光染料和可吸收紫外至蓝色区域的光以发出荧光的第二荧光染料，其中第一亚珀尔荧光染料吸收包含第二荧光染料发出的荧光的光以发出荧光。
• COLOR CONVERTING MATERIAL COMPOSITION AND COLOR CONVERTING MEDIUM INCLUDING SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1881741A1

  公开（公告）日：2008-01-23

  A color converting material composition including: a light-transmissible matrix; a fluorescent semiconductor nanocrystal which absorbs at least light in a first wavelength region; and an organic fluorescent dye which absorbs at least light in a second wavelength region.

  一种色彩转换材料组合物，包括：透光基质；至少能吸收第一波长区域光线的荧光半导体纳米晶体；以及至少能吸收第二波长区域光线的有机荧光染料。
• Red Fluorescence Conversion Medium, Color Conversion Substrate Using Same and Light-Emitting Device
  申请人：Katano Junichi

  公开号：US20080252198A1

  公开（公告）日：2008-10-16

  A red fluorescence conversion medium including; a light-transmitting medium, a first perylene fluorescent dye that emits red fluorescence, and a second fluorescent dye that absorbs light in a ultraviolet to blue region to emit fluorescence, wherein the first perylene fluorescent dye absorbs light containing the fluorescence emitted by the second fluorescent dye to emit fluorescence.