nickel(II)-bis[3-acetylpyridine-[O-cyclopentyl-(4-methoxyphenyl)dithiophosphonate]] | 927178-06-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: nickel(II)-bis[3-acetylpyridine-[O-cyclopentyl-(4-methoxyphenyl)dithiophosphonate]]
• CAS: 927178-06-1
• 化学式: C₃₈H₄₆N₂NiO₆P₂S₄
• 分子量: 875.695
• InChiKey: ZPEMZEWTBWCMRK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-乙酰基吡啶 、 nickel(II)-bis[O-cyclopentyl-(4-methoxyphenyl)dithiophosphonate] 以 二氯甲烷 为溶剂， 以80%的产率得到nickel(II)-bis[3-acetylpyridine-[O-cyclopentyl-(4-methoxyphenyl)dithiophosphonate]]
  参考文献：
  名称：

  Synthesis and characterization of Ni(II), Zn(II), and Cd(II) complexes with dithiophosphonate derivatives

  摘要：

  Ammonium salts of p-methoxyphenyldithiophosphonic acid O-alkyl esters (H3CO-C6H4-(RO)P(S)S-NH4+; R = C2H5, -CH2CH2CH2CH2-, and cyclopentyl) and their complexes with Ni2+, Cd2+, and Zn2+ were prepared. 2,4-Bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide, the so-called Lawesson reagent, was treated with the corresponding alcohol to give the O-alkyl ester of the acid. Dry NH3 was then purged through the solution of this ester to form the ammonium salt of the O-alkyl dithiophosphonic acids. Nickel complexes of these ligands were formed in acetic acid, while zinc and cadmium complexes were formed in water and an ethanol medium, respectively. The geometry of the coordinated atoms was square planar with Ni2+ and tetrahedral with Zn2+ and Cd2+. Using an alkanediol, two dithiophosphonic acids were bridged, thus forming a ligand with four S atoms for coordination. The zinc and cadmium complexes of these tetradentate ligands were also synthesized.

  DOI：

  10.1134/s1070328406060078