2-benzoyl-3-phenyl-cyclopropanecarboxylic acid | 13304-18-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-benzoyl-3-phenyl-cyclopropanecarboxylic acid
• 英文别名: 2-Benzoyl-3-phenyl-cyclopropancarbonsaeure；2-Benzoyl-3-phenylcyclopropane-1-carboxylic acid
• CAS: 13304-18-2
• 化学式: C₁₇H₁₄O₃
• 分子量: 266.296
• InChiKey: MZBZPIBUACKDAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-benzoyl-3-phenyl-cyclopropanecarboxylic acid 在 Pd-BaSO₄ 、 sodium carbonate 作用下， 生成 2-苄基-4-氧代-4-苯基丁酸甲酯
  参考文献：
  名称：

  Two possible hydrothermal vents in the northern Okinawa Trough

  摘要：

  As the Okinawa Trough is a back-are basin in early spreading, modern submarine hydrothermal activity and minerallization have many characteristics which have aroused wide attention. Up to now three well-known hydrothermal venting areas are all located in the middle part of the trough, During two cruise investigations to map and sample the seafloor numbers of Calyptogena sp, shells were dredged at two sites in the northern trough with comparatively thicker crust and numerous submarine volcanoes. Based on the fact that Calyptogena sp, is only observed around the hydrothermal vents and lives on hydrothermal activities, it is predicted that there is the possibility of modern hydrothermal activities in the northern part of the trough. In this note, the shell is carefully characterized and the sample locations with possible hydrothermal activity are given. it Is pointed out that the research of biogenic fossils to trace hydrothermal activity changes in venting time, strength fluctuations, evolution In chemical compositions and so on should be stressed in the future in addition to the study of the ecological characteristics of hydrothermal organisms.

  DOI：

  10.1007/bf02900472
• 作为产物：
  描述：

  ethyl 2t-benzoyl-3c-phenylcyclopropane-1r-carboxylate 、 alkaline earth salt of/the/ methylsulfuric acid 生成 2-benzoyl-3-phenyl-cyclopropanecarboxylic acid
  参考文献：
  名称：

  Kohler, Steele, Journal of the American Chemical Society, 1919, vol. 41, p. 1097

  摘要：

  DOI：

文献信息

• Kohler,Conant, Journal of the American Chemical Society, 1917, vol. 39, p. 1410
  作者：Kohler,Conant

  DOI：——

  日期：——
• Kohler, American Chemical Journal, 1911, vol. 46, p. 486
  作者：Kohler

  DOI：——

  日期：——
• Rai, K. M. Lokanatha; Anjanamurthy, C.; Radhakrishna, P. M., Synthetic Communications, 1990, vol. 20, # 9, p. 1273 - 1277
  作者：Rai, K. M. Lokanatha、Anjanamurthy, C.、Radhakrishna, P. M.

  DOI：——

  日期：——
• Kautsky; Thiele, Angewandte Chemie, 1924, vol. 37, p. 540
  作者：Kautsky、Thiele

  DOI：——

  日期：——
• Kautsky; Thiele, Zeitschrift fur Anorganische und Allgemeine Chemie, 1925, vol. 144, p. 202
  作者：Kautsky、Thiele

  DOI：——

  日期：——