| 1252654-93-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1252654-93-5
• 化学式: C₅₀H₃₈Cl₂Cu₂N₄O₁₆
• 分子量: 1148.87
• InChiKey: FRSOVKIQZRWSQG-ARKUHFRSSA-J

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 2-((2-((1-[(E)-(hydroxyimino)methyl]-2-naphthyl)methoxy)-4-((1-[(E)-(hydroxyimino)methyl]-2-naphthyl)oxy)-3-[((1-[(E)-(hydroxyimino)methyl]-2-naphthyl)oxy)methyl]but-2-en-1-yl)oxy)-1-naphthaldehyde oxime 在 N(C₂H₅)3 作用下， 以 乙醇 为溶剂， 以64.7%的产率得到
  参考文献：
  名称：

  Synthesis, characterization and properties of tetra((1-hydroxyimino-methylnaphthalen-2-yloxy)methyl)ethene and its homo-dinuclear metal complexes: A combined experimental and theoretical investigation

  摘要：

  Tetra((1-hydroxyiminomethylnaphthalen-2-yloxy)methyl)ethene (THIMNYOME), H4L, was synthesized by the agents of 2-hydroxy-1-naphtaldehyde, tetra(bromomethyl)ethene and hydroxylamine hydrochloride in two steps. Characterization of THIMNYOME and its dinuclear complexes was made by elemental analyses. IR, H-1- and C-13 NMR, UV-vis, electrospray ionisation mass spectra, molar conductivities and magnetic susceptibility measurements. In the light of these results, it was suggested that the ligand coordinate to each metal atom by the two ether oxygen, two nitrogen atoms of oxime imine (C=N) and an axial oxygen of perchlorate to form pseudo square-pyramidal complexes with Ni(II), Cu(II) and Zn(II). Molar conductivity measurements reveal that all the complexes are non-electrolytes. In addition, the full geometric optimization of the tetraoxime ligand (4) has been made by the B3LYP/6-31G(d) level in order to establish a stable conformation.Additionally, all the complex structures have been studied in the B3LYP/LANL2DZ level. NBO charge distribution and the characteristics of frontier molecular orbitals of these complexes have also been investigated in order to see the electrons movement between ligand and metal atom in the same level. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2010.07.002