3-[o-aminophenyliminomethyl]-4-hydroxy-6-methyl-2-(1H)quinolone | 193528-38-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 3-[o-aminophenyliminomethyl]-4-hydroxy-6-methyl-2-(1H)quinolone
• 英文别名: 3-[(2-aminophenyl)iminomethyl]-4-hydroxy-6-methyl-1H-quinolin-2-one
• CAS: 193528-38-0
• 化学式: C₁₇H₁₅N₃O₂
• 分子量: 293.325
• InChiKey: FUCRVKMPJVFKIY-UHFFFAOYSA-N

物化性质

• 沸点：
  568.5±50.0 °C(Predicted)
• 密度：
  1.32±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  87.7
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  硫酸氧钒水合物 、 3-[o-aminophenyliminomethyl]-4-hydroxy-6-methyl-2-(1H)quinolone 以 乙醇 为溶剂， 以37%的产率得到
  参考文献：
  名称：

  A Novel Type Half-Unit Schiff Base Ligand, 3-[o-Aminophenyliminomethyl]-4-Hydroxy-6-Methyl-2-(1H)-Quinolone and its Metal Complexes. Part IVa

  摘要：

  A novel half-unit Schiff base ligand derived from 6-methyl-3-formyl-4-hydroxy-2-(1H)quinolone and o-phenylenediamine was prepared. The Schiff base acts as a monobasic ligand. Metal complexes of the type [MLX](2), M = Cu(II), Ni(II) or Fe(III); X = Cl or OAc were obtained by the reaction of metal acetates or chlorides with the ligand, with the ligand behaving as a terdentate. However, the reaction of M(ClO4)(2) . 6H(2)O, M = Cu(II) or Ni(II), VOSO4 and UO2(OAc)(2) . 2H(2)O with the ligand, yielded complexes of the type [ML2], where the ligand behaves as a bidentate. The ligand and its metal complexes were characterized by elemental analyses, UV-visible, IR and mass spectra. Also, magnetic susceptibilities of the metal complexes were determined.

  DOI：

  10.1080/00945719708000235