methyl cis-β-chloro-α-methylacrylate | 67832-64-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: methyl cis-β-chloro-α-methylacrylate
• 英文别名: trans-3-chloro-2-methyl-acrylic acid methyl ester；trans-3-Chlor-2-methyl-acrylsaeure-methylester；3-Chlor-2-methyl-acrylsaeure-methylester；Methyl-cis-2-methyl-3-chlorpropenoat；Methyl e-2-methyl-3-chloropropenoate；methyl (E)-3-chloro-2-methylprop-2-enoate
• CAS: 67832-64-8
• 化学式: C₅H₇ClO₂
• 分子量: 134.562
• InChiKey: MJFYKGUKOYPESV-ONEGZZNKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  methyl cis-β-chloro-α-methylacrylate 在 硫酸 、 氢氟酸 、 六氯三聚氰胺 、 锌 作用下， 生成 methyl cis-β-fluoro-α-methylacrylate
  参考文献：
  名称：

  Boguslavskaya, L. S.; Chernov, A. N.; Krom, E. N., Journal of Organic Chemistry USSR (English Translation), 1980, p. 1392 - 1397

  摘要：

  DOI：
• 作为产物：
  描述：

  β-chloro-α-hydroxy-isobutyric acid methyl ester 在 吡啶 、 氯化亚砜 作用下， 生成 methyl cis-β-chloro-α-methylacrylate
  参考文献：
  名称：

  Hurd; Rector, Journal of Organic Chemistry, 1945, vol. 10, p. 444

  摘要：

  DOI：

文献信息

• Novel guanidine type compound, toner for developing electrostatic images, developer for developing electrostatic images, apparatus unit, electrophotographic apparatus and facsimile apparatus
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP0423756A1

  公开（公告）日：1991-04-24

  A guanidine type compound has the following formula: wherein R¹ to R⁸ are each a hydrogen atom, an alkyl group, an amino group, an alkoxy group, a substituted or unsubstituted aryl group, and R¹ to R⁸ may be the same as or different from each other and together may form a ring with the adjacent substituents; X is a halogen atom, a hydroxyl group or an alkoxy group; and m and n are each an integer having a value of 1 to 8. The guanidine compound is employed in a toner for electrostatic development and the toner can be used in an electrophotographic apparatus including a facsimile apparatus for receiving image information from an electrophotographic copier.

  一种胍类化合物具有下式： 其中 R¹ 至 R⁸ 各为氢原子、烷基、氨基、烷氧基、取代或未取代的芳基，且 R¹ 至 R⁸ 可彼此相同或不同，并可与相邻取代基共同形成环；X 为卤素原子、羟基或烷氧基；以及 m 和 n 各为数值为 1 至 8 的整数。胍基化合物可用于静电显影的调色剂中，该调色剂可用于电子照相设备中，包括从电子照相复印机接收图像信息的传真设备。
• Arndt; Ozansoy; Uestuenyar, Istanbul Universitesi Fen Fakultesi Mecmuasi, 1939, vol. 4, p. 87
  作者：Arndt、Ozansoy、Uestuenyar

  DOI：——

  日期：——
• Boguslavskaya,L.S. et al., Journal of Organic Chemistry USSR (English Translation), 1978, vol. 14, # 7, p. 1347 - 1352
  作者：Boguslavskaya,L.S. et al.

  DOI：——

  日期：——
• DEGRADABLE POLYCATIONS DERIVED FROM AMINO ACID VINYL ESTERS
  申请人：Wisconsin Alumini Research Foundation

  公开号：US20130184423A1

  公开（公告）日：2013-07-18

  Described herein are the synthesis and polymerization of a series of N-Boc-protected amino acid vinyl ester (BAAVE) monomers. Homopolymers and heteropolymers containing the monomers are described, particularly heteropolymers with vinyl ester monomers such as vinyl acetate. Deprotection can be used to produce hydrophilic and hydrophobic polymers that are particular useful in biological applications such as cellular delivery of biological materials.
• US8796405B2
  申请人：——

  公开号：US8796405B2

  公开（公告）日：2014-08-05