1,3-bis(4-iodo-3,5-dimethylpyrazol-1-yl)propanedinitratocopper | 1356614-03-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,3-bis(4-iodo-3,5-dimethylpyrazol-1-yl)propanedinitratocopper
• CAS: 1356614-03-3
• 化学式: C₁₃H₁₈CuI₂N₆O₆
• 分子量: 671.678
• InChiKey: HWPRRYXGFNBHFM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,3-bis(4-iodo-3,5-dimethylpyrazol-1-yl)propane 、 copper(II) nitrate trihydrate 以 丙酮 为溶剂， 以94%的产率得到1,3-bis(4-iodo-3,5-dimethylpyrazol-1-yl)propanedinitratocopper
  参考文献：
  名称：

  Synthesis and crystal structure of discrete complexes and coordination polymers containing 1,3-bis(pyrazol-1-yl)propane ligands

  摘要：

  Complexes of 1,3-bis(pyrazole-1-yl)propane ligands with copper(II), nickel(II) and cobalt(II) ions were prepared and characterized by spectral methods and X-ray crystallography. Ligands with metal nitrates are chelating bidentate forming discrete complexes with eight-membered metallocycles. The structure of nickel(II) nitrate complex with 1,3-bis(3,5-dimethylpyrazol-1-yl)propane was determined by X-ray crystallography. In case of copper(II) chloride 1,3-bis(pyrazole-1-yl)propane adopted a bridging bidentate mode and a linear coordination polymer containing 16-membered metallocycles was formed. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.039