[Pd(3-(1-amino-2,2,2-trichloroethylidene)pentane-2,4-dione(-H)-N,O)2] | 1123307-27-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Pd(3-(1-amino-2,2,2-trichloroethylidene)pentane-2,4-dione(-H)-N,O)2]
• CAS: 1123307-27-6
• 化学式: C₁₄H₁₄Cl₆N₂O₄Pd
• 分子量: 593.414
• InChiKey: AATKZOXHNFXHQR-UHFFFAOYSA-N

物化性质

• 熔点：
  150 °C (decomp)

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  palladium diacetate 、 3-(1-amino-2,2,2-trichloroethylidene)pentane-2,4-dione 以 乙醇 为溶剂， 以45%的产率得到[Pd(3-(1-amino-2,2,2-trichloroethylidene)pentane-2,4-dione(-H)-N,O)2]
  参考文献：
  名称：

  N,O versus O,O coordination in β-imino diketonato complexes: Role of the metal center and of the imino substituent

  摘要：

  beta-Imino carbonyl enolato metal(II) complexes of general formula [M((RCO)(R'CO)CC(R '') NH)(2)] (M = Mn, Fe, Co, Ni, Cu, Zn, Pd, R = R' = Me, R '' = CCl(3); M = Cu, Pd, R = R' = Me, R '' = PhCO; R = Me, R' = Ph, R '' = PhCO; R = R' = Ph, R '' = PhCO) are easily synthesized by the reaction of metal(II) acetates with the proper beta-enaminodiones in 1/2 molar ratio in ethanol at room temperature. In all the cases the trifunctional NOO beta-imino carbonyl enolate ligand acts as bidentate to give ML(2) complexes, whose structure depends on the metal center and on the nature of the substituent R '' at the imino carbon. With R '' = CCl(3) an O,O coordination is observed for all the metal centers but one, in fact palladium(II) exhibits an N,O coordination through the imino nitrogen and one keto oxygen. By contrast with R '' = PhCO the ligand is always coordinated through the imino nitrogen and one keto oxygen atom. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.003