7,7'-((propane-1,3-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methylquinolin-8-ol) | 370577-35-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7,7'-((propane-1,3-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methylquinolin-8-ol)
• CAS: 370577-35-8
• 化学式: C₂₅H₂₄N₄O₂
• 分子量: 412.491
• InChiKey: ARBSRPVKEVCMSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.74
• 重原子数：
  31.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  90.96
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  硫酸氧钒水合物 、 7,7'-((propane-1,3-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methylquinolin-8-ol) 在 LiOH*H₂O 作用下， 以 乙醇 、 水 为溶剂， 以72%的产率得到oxovanadium(IV) 7,7'-((propane-1,3-diylbis(azaneylylidene))bis(methaneylylidene))bis(2-methylquinolin-8-olate)
  参考文献：
  名称：

  METAL COMPLEXES OF NOVEL SYMMETRICAL SCHIFF BASE LIGANDS

  摘要：

  Two novel symmetrical Schiff base ligands, H2L1 and H2L2 with tetradentate N2O2 and pentadentate N3O2 coordinating sites were prepared by the reaction of the aldehyde 2-methyl-7-formyl-8-hydroxy-quinoline with 1,3-diaminopropane or diethylenetriamine, respectively, in the molar ratio 2: 1. Cu(II), Ni(II), Co(II), Mn(II), Fe(III) and VO(IV) complexes of both ligands were synthesized. The ligands and their metal complexes were characterized by elemental analyses, IR, UV-Vis, ESR, NMR and mass spectra and also by magnetic moment measurements. Both ligands behave as tetradentate ones when coordinating metal cations. The ligand H2L1 has a smaller cavity than the ligand H2L2, thus the former ligand yielded mononuclear products, through chelation of one ligand molecule to a metal cation, while the latter ligand yielded binuclear products, through the coordination of two metal cations to two ligand molecules. Each of the Fc(III) cations was coordinated to three halves of both ligand molecules yielding also a mononuclear product with ligand H2L1 and a binuclear product with ligand H2L2. Either mononuclear or binuclear complex molecules link together forming polymeric chains. The mononuclear and binuclear complex forms were well manifested in the ESR spectra of the vanadyl complexes. The polymeric structures of the metal complexes led to an enhanced decrease of their magnetic moments through antiferromagnetic exchange between neighbouring metal cations.

  DOI：

  10.1081/sim-100104858