Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-[(1,3-dimethyl-2,4,6-trioxo-tetrahydro-pyrimidin-5-ylidenemethyl)-amino]-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yl ester | 342640-41-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-[(1,3-dimethyl-2,4,6-trioxo-tetrahydro-pyrimidin-5-ylidenemethyl)-amino]-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yl ester
• 英文别名: [(2R,3S,4R,5R,6R)-3,4-diacetyloxy-5-[(1,3-dimethyl-2,4,6-trioxo-1,3-diazinan-5-ylidene)methylamino]-6-(2,2,2-trichloroethanimidoyl)oxyoxan-2-yl]methyl acetate
• CAS: 342640-41-9
• 化学式: C₂₁H₂₅Cl₃N₄O₁₁
• 分子量: 615.809
• InChiKey: UILJUJOIISKZFM-VFCJXBEMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.39
• 重原子数：
  39.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  190.93
• 氢给体数：
  2.0
• 氢受体数：
  13.0

反应信息

• 作为反应物：
  描述：

  methyl 2-azido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside 、 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-[(1,3-dimethyl-2,4,6-trioxo-tetrahydro-pyrimidin-5-ylidenemethyl)-amino]-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yl ester 在 三氟甲磺酸三甲基硅酯 作用下， 以 二氯甲烷 为溶剂， 生成 、
  参考文献：
  名称：

  Application of novel, N -DTPM protected d -glucosamine building blocks in oligosaccharide synthesis

  摘要：

  A study of glycosylation reactions was performed, using novel N-DTPM protected glucosamine donors 1-3 and D-Gal- and D-Glu-series. The accepters 4-9 ranging from achiral primary alcohols to various alcohols within the D-GlcNAc-: results show high yielding reactions with good beta -selectivities. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00367-7
• 作为产物：
  描述：

  在 哌啶 、 吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 92.0h， 生成 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-[(1,3-dimethyl-2,4,6-trioxo-tetrahydro-pyrimidin-5-ylidenemethyl)-amino]-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yl ester
  参考文献：
  名称：

  Application of novel, N -DTPM protected d -glucosamine building blocks in oligosaccharide synthesis

  摘要：

  A study of glycosylation reactions was performed, using novel N-DTPM protected glucosamine donors 1-3 and D-Gal- and D-Glu-series. The accepters 4-9 ranging from achiral primary alcohols to various alcohols within the D-GlcNAc-: results show high yielding reactions with good beta -selectivities. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(01)00367-7